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EC number: 413-110-2 | CAS number: 135861-56-2
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Endpoint summary
Administrative data
Description of key information
The information on toxicity of this substance leads to conclusion that in overall this substance is of low toxicity.
Key value for chemical safety assessment
Repeated dose toxicity: via oral route - systemic effects
Link to relevant study records
- Endpoint:
- chronic toxicity: oral
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: see 'Remark'
- Remarks:
- The information of this endpoint has been provided by ECHA as a result of an inquiry, thus the full access to data in the report is not accessible to the registrant. However the reliability is estimated to be at level 1: Study conducted in accordance with generally accepted scientific principles. Possible deficiencies do not affect the quality of relevant results.
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity Study in Rodents)
- GLP compliance:
- yes
- Limit test:
- no
- Species:
- rat
- Strain:
- Sprague-Dawley
- Sex:
- male/female
- Route of administration:
- oral: unspecified
- Vehicle:
- not specified
- Details on oral exposure:
- Method of administration was dietary admixture.
- Analytical verification of doses or concentrations:
- not specified
- Duration of treatment / exposure:
- 90 days
- Frequency of treatment:
- Dosing regime: 7days/week
- No. of animals per sex per dose:
- Male: 30 animals at 0 mg/kg bw/day
Male: 20 animals at 123.1 mg/kg bw/day
Male: 20 animals at 406.4 mg/kg bw/day
Male: 20 animals at 1261.3 mg/kg bw/day
Female: 30 animals at 0 mg/kg bw/day
Female: 20 animals at 135.7 mg/kg bw/day
Female: 20 animals at 478.5 mg/kg bw/day
Female: 20 animals at 1479.2 mg/kg bw/day - Control animals:
- yes
- Clinical signs:
- no effects observed
- Mortality:
- no mortality observed
- Body weight and weight changes:
- effects observed, treatment-related
- Description (incidence and severity):
- A decreased body weight gain was noted for group 3 males (not significant) and group 4 males and females (statistically significant)
- Food consumption and compound intake (if feeding study):
- not specified
- Food efficiency:
- not specified
- Water consumption and compound intake (if drinking water study):
- not specified
- Ophthalmological findings:
- not specified
- Haematological findings:
- effects observed, treatment-related
- Description (incidence and severity):
- A very slight increase of blood urea nitrogen was noted in group 4 (not significant when compared to controls). This effect was reversible after 4 weeks without treatment.
- Clinical biochemistry findings:
- not specified
- Urinalysis findings:
- not specified
- Behaviour (functional findings):
- not specified
- Organ weight findings including organ / body weight ratios:
- no effects observed
- Gross pathological findings:
- not specified
- Histopathological findings: non-neoplastic:
- no effects observed
- Histopathological findings: neoplastic:
- no effects observed
- Details on results:
- Considering weakness of the reactions noted during the study, the histopathological results (to be provided by end of November 1993) should not modify the classification of the substance. Only some kidney lesions may be noted at the highest does level group.
- Dose descriptor:
- NOAEL
- Effect level:
- 406.4 mg/kg bw/day (nominal)
- Based on:
- not specified
- Sex:
- male/female
- Dose descriptor:
- NOEL
- Effect level:
- 123.1 mg/kg bw/day (nominal)
- Based on:
- not specified
- Sex:
- male/female
- Critical effects observed:
- not specified
- Conclusions:
- Not classified as hazardous.
- Executive summary:
In the study done according to OECD Guideline 408, the animals (rats) were feeded during 90 days, 7 days a week.
The 6 groups of 20 animals each (3 groups of males and 3 groups of females) ingested different doses of the substance: Male groups intake was 123.1 mg/kg bw/day (group 2) , 406.4 mg/kg bw/day (group 3) and 1261.3 mg/kg bw/day (group 4); Female groups intake was 135.7 mg/kg bw/day (group 2) , 478.5 mg/kg bw/day (group 3), 1479.2 mg/kg bw/day (group 4) The control groups (group 1) were from 30 animals each, male and female. During the feeding period a decreased body weight gain was noted for group 3 males (not significant) and group 4 males and females (statistically significant). No notice of deaths were observed in the control group or in the testing groups. A very slight increase of blood urea nitrogen was noted in group 4 (not significant when compared to controls). This effect was reversible after 4 weeks without treatment.According to the information available the reactions observed during the study is considered weak, and lead to the conclusion that the substance is not hzardous. At the time that this study was submitted to the authorities, the histopathological results were not available but considering this weakness of the reactions noted during the study it was not expected that they should modify the classification of the substance. Only some kidney lesions may be noted at the highest does level group.
The result of this study allowed to obtian a NOEL of 123.1 mg/kg bw/day and a NOAEL of 406.4 mg/kg bw/day.
Reference
Endpoint conclusion
- Endpoint conclusion:
- no adverse effect observed
- Dose descriptor:
- NOAEL
- 406.4 mg/kg bw/day
- Study duration:
- subchronic
- Species:
- rat
- Quality of whole database:
- The key study is GLP compliant and scored Klimisch 1 for reliability.
Repeated dose toxicity: inhalation - systemic effects
Endpoint conclusion
- Endpoint conclusion:
- no study available
Repeated dose toxicity: inhalation - local effects
Endpoint conclusion
- Endpoint conclusion:
- no study available
Repeated dose toxicity: dermal - systemic effects
Endpoint conclusion
- Endpoint conclusion:
- no study available
Repeated dose toxicity: dermal - local effects
Endpoint conclusion
- Endpoint conclusion:
- no study available
Additional information
There are two available repeated dose studies for oral route. For inhalation route and dermal route there isn't any data on repeated exposure. This substance is considered of an overall low toxicity and this fact is supported by all available toxicity tests.
The study done according to EU Test Method B.7 the animals (rats) were feeded with the substance during 28 days, 7 days a week. The controls after exposure showed a few effects on the kidney but there were not considered significant because this fact was observed too in the control groups and was atributed to the rats strain.
The result of the study allowed to obtain a NOEL of 200 mg/kg bw/day and a NOAEL of 1000 mg/kg bw/day.
In the study done according to OECD Guideline 408, the animals (rats) were feeded during 90 days, 7 days a week.
During the feeding period a decreased body weight gain was noted for group 3 males (not significant) and group 4 males and females (statistically significant). No notice of deaths were observed in the control group or in the testing groups. A very slight increase of blood urea nitrogen was noted in group 4 (not significant when compared to controls). This effect was reversible after 4 weeks without treatment.According to the information available the reactions observed during the study is considered weak, and lead to the conclusion that the substance is not hazardous. At the time that this study was submitted to the authorities, the histopathological results were not available but considering this weakness of the reactions noted during the study it was not expected that they should modify the classification of the substance. Only some kidney lesions may be noted at the highest does level group.
The result of this study allowed to obtain a NOEL of 123.1 mg/kg bw/day and a NOAEL of 406.4 mg/kg bw/day.
Justification for selection of repeated dose toxicity via oral route - systemic effects endpoint:
The repeated dose study selected is 90-days repeated dosed instead of 28-days which allows a to a better definition of long-term effects.
Repeated dose toxicity: via oral route - systemic effects (target organ) urogenital: kidneys
Justification for classification or non-classification
The available experimental test data are reliable and suitable for classification purposes under Regulation 1272/2008. The values obtained have been compared to criteria set up in the Annex I of the Regulation (section 3.9).
As a result the substance is not considered to be classified for repeated dose toxicity under Regulation (EC) No. 1272/2008.Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.