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Auto flammability

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Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
15 June 2016 - 12 April 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
Deviations:
no
Qualifier:
according to guideline
Guideline:
IEC 60079-4 (Electrical apparatus for explosive gas atmospheres. Part 4: Method of test for ignition temperature)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
- Batch n°: A16EB1463
- Analytical purity: 96.3% (GC chromatographic purity)
- Expiration date: 2017-09-12
- Storage condition: at room temperature
Auto-ignition temperature:
470 °C
Atm. press.:
>= 1 025.5 - <= 1 028.4 hPa

Preliminary test

The estimated auto-ignition temperature was 470°C.

Main study

Ignition of the test item within 5 min after introduction was observed with each sample volume and with each test a minimum auto-ignition temperature was obtained. The maximum deviation between the three values was < 20°C. According to the guidelines, no further testing was required.

The lowest temperature at which ignition of the test item occurred was 471°C. This temperature was rounded down to the nearest multiple of 5°C giving an auto-ignition temperature of the test item of 470°C.

Conclusions:
A commercially available auto-ignition temperature apparatus was used for the determination of the degree of auto-ignitability of JNJ-118872-AAA (T000749).

The test item is determined to be auto-ignitable with an auto-ignition temperature of 470°C at 1025.5 – 1028.4 hPa.

Description of key information

Based on a GLP study (K1, Reingruber, 2017) based on the methods EC A.15, DIN Guide 51794 and IEC standard 79 -4, the test item is determined to be auto-ignitable with an auto-ignition temperature of 470°C at 1025.5 – 1028.4 hPa.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
470 °C

Additional information