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Physical & Chemical properties

Vapour pressure

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Administrative data

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2011
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions
Justification for type of information:
The study was conducted according to an internationally recognised method. The substance is considered to be adequately characterised. Validation applies with restrictions due to a large extrapolation of the vapour pressure at 25°C.
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Version / remarks:
2008
Deviations:
not specified
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Version / remarks:
2006
Deviations:
not specified
GLP compliance:
no
Type of method:
dynamic method
Key result
Temp.:
25 °C
Vapour pressure:
0.022 hPa

Temperature [°C]

Pressure [hPa]

122.0

22.1

126.5

27.5

136.4

41.5

144.0

60.0

155.0

89.0

162.5

119.0 

165.0

137.8  

172.0   

168.6 

178.1 

210.2

An extrapolation is made using a non-linear regression with the measuring points according to the permutation matrix of Fremann-Carrol and by Antoine equation to obtain the vapour pressure at 25°C.

Conclusions:
The vapour pressure was determined to be 0.0225 hPa (2.25 Pa) at 25 °C.
Executive summary:

The vapour pressure of the test substance was measured according to OECD 104/EU A4 guideline, dynamic method. The result at 25°C was extrapolated from a series of measurements between 22 and 210 hPa,


corresponding to 122 to 178°C.


The vapour pressure was determined to be 0.0225 hPa (2.25 Pa) at 25 °C.

Description of key information

The vapour pressure was determined to be 0.0225 hPa (2.25 Pa) at 25 °C (extrapolation).

Key value for chemical safety assessment

Vapour pressure:
0.022 hPa
at the temperature of:
25 °C

Additional information

A reliable experimental study, conducted according to a recognized OECD/EU method, is available. Despite restrictions due to distant extrapolation, it is considered as a key study. The result is retained

as key data.