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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Vapour pressure

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Remarks:
Senatsverwaltung für Gesundheit, Berlin
Type of method:
effusion method: vapour pressure balance
Temp.:
20 °C
Vapour pressure:
0 Pa
Remarks on result:
other: extrapolated value

The temperature dependence on the basis of the experimental data fits to the equation:

log P = 6808*(1 /T) + 17.57

t [°C]

P(Pa)

95 % CI

20*

2.2 ·10-6

9.3 ·10-7- 5.1 ·10-6

25*

5.5 ·10-6

2.5 ·10-6- 1.2 ·10-5

30*

1.3 ·10-5

6.3 ·10-6- 2.6 ·10-5

66

2.9 ·10-3

2.1 · 10- 3- 4.5 ·10-3

75

1.08 ·10-2

7 ·10-3 - 1.5 ·10-2

94*

0.105

6.8 ·10-2- 0.16

104*

0.32

0.196 - 0.53

 

*) - extrapolated values of vapour pressure

t - temperature (°C)

p - vapour pressure (Pa)

95% CI - 95 % confidence interval

 

The good agreement of the experiments at different temperatures provides evidence that the samples being measured are sufficiently pure. They are not decomposing in the respective range of temperatures.

Description of key information

0.0000022 Pa at 20 °C 

Key value for chemical safety assessment

Vapour pressure:
0 Pa
at the temperature of:
20 °C

Additional information

OECD Guideline 104 (Vapour Pressure Curve); effusion method (vapour pressure balance)

- value estimated according to the Antoine equation