Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Vapour pressure

Currently viewing:

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
11-Apr-2005
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
GLP compliance:
yes (incl. QA statement)
Remarks:
BAYERISCHES LANDESAMT FUR ARBEITSSCHUTZ, ARBEITSMEDIZIN UND SICHERHEITSTECHNIK
Type of method:
dynamic method
Temp.:
20 °C
Vapour pressure:
12.9 hPa
Temp.:
25 °C
Vapour pressure:
19 hPa

Results

Estimated vapour pressure:    12.9 hPa at 20 °C

                                          19.0 hPa at 25 °C

 

Formula of regression: Iog p [hPa] = -2905.76 × 1/T [1/K] + 11.02367

 

Raw data:

Data point

Boiling temperature

T (°C)

Vapour pressure

P (hPa)

1.

7

4.2

2.

19

12

3.

30

30

4.

49

102

5.

65

263

6.

61

202

7.

56

156

8.

43

71

9.

25

19

10.

14

8

 

Conversion of the raw data:

Data point

T [K]

1/T [1/K]

log p [hPa]

1.

280.15

0.003570

0.62325

2.

292.15

0.003423

1.07918

3.

303.15

0.003299

1.47712

4.

322.15

0.003104

2.00860

5.

338.15

0.002957

2.41996

6.

334.15

0.002993

2.30535

7.

329.15

0.003038

2.19312

8.

316.15

0.003163

1.85126

9.

298.15

0.003354

1.27875

10.

287.15

0.003483

0.90309

 

 

Transition (change of state, decomposition) during measurement:

 

Observation of a transition: No

Conclusions:
A vapour pressure of 12.9 hPa at 20°C and 19.0 hPa at 25 °C was determined in a reliable study conducted according to an appropriate test protocol, and in compliance with GLP.

Description of key information

Trimethylsilanol: 19 hPa at 25°C (Dynamic method, OECD 104)

Key value for chemical safety assessment

Vapour pressure:
19 hPa
at the temperature of:
25 °C

Additional information

For the silanol hydrolysis product vapour pressure values of 12.9 hPa at 20°C and 19 hPa at 25°C were determined by dynamic method according to OECD 104, EU Method A.4.