Registration Dossier

Administrative data

First-aid measures

SWALLOWED
• If swallowed do NOT induce vomiting.
• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
• Observe the patient carefully.
• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
• Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
• Seek medical advice.
EYE
» If this product comes in contact with the eyes:
• Wash out immediately with fresh running water.
• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
• If pain persists or recurs seek medical attention.
• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
SKIN
» If skin contact occurs:
• Immediately remove all contaminated clothing, including footwear.
• Flush skin and hair with running water (and soap if available).
• Seek medical attention in event of irritation.
INHALED
• If fumes or combustion products are inhaled remove from contaminated area.
• Lay patient down. Keep warm and rested.
• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
• Transport to hospital, or doctor.
NOTES TO PHYSICIAN
» Treat symptomatically.

Fire-fighting measures

EXTINGUISHING MEDIA
• Foam.
• Dry chemical powder.
• BCF (where regulations permit).
• Carbon dioxide.
• Water spray or fog - Large fires only.
FIRE FIGHTING
• Alert Fire Brigade and tell them location and nature of hazard.
• Wear full body protective clothing with breathing apparatus.
• Prevent, by any means available, spillage from entering drains or water course.
• Use water delivered as a fine spray to control fire and cool adjacent area.
• Avoid spraying water onto liquid pools.
• DO NOT approach containers suspected to be hot.
• Cool fire exposed containers with water spray from a protected location.
• If safe to do so, remove containers from path of fire.
FIRE/EXPLOSION HAZARD
• Combustible.
• Slight fire hazard when exposed to heat or flame.
• Heating may cause expansion or decomposition leading to violent rupture of containers.
• On combustion, may emit toxic fumes of carbon monoxide (CO).
• May emit acrid smoke.
• Mists containing combustible materials may be explosive.
Combustion products include: carbon dioxide (CO2), phosphorus oxides (POx), other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
• Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
PERSONAL PROTECTION
Glasses:
Chemical goggles.
Gloves:
Respirator:
Type A Filter of sufficient capacity

Accidental release measures

MINOR SPILLS
• Remove all ignition sources.
• Clean up all spills immediately.
• Avoid breathing vapors and contact with skin and eyes.
• Control personal contact by using protective equipment.
• Contain and absorb spill with sand, earth, inert material or vermiculite.
• Wipe up.
• Place in a suitable, labeled container for waste disposal.
MAJOR SPILLS
• Clear area of personnel and move upwind.
• Alert Fire Brigade and tell them location and nature of hazard.
• Wear breathing apparatus plus protective gloves.
• Prevent, by any means available, spillage from entering drains or water course.
• No smoking, naked lights or ignition sources.
• Increase ventilation.
• Stop leak if safe to do so.
• Contain spill with sand, earth or vermiculite.
• Collect recoverable product into labeled containers for recycling.
• Absorb remaining product with sand, earth or vermiculite.
• Collect solid residues and seal in labeled drums for disposal.
• Wash area and prevent runoff into drains.
• If contamination of drains or waterways occurs, advise emergency services.

Handling and storage

PROCEDURE FOR HANDLING
• Avoid all personal contact, including inhalation.
• Wear protective clothing when risk of exposure occurs.
• Use in a well-ventilated area.
• Prevent concentration in hollows and sumps.
• DO NOT enter confined spaces until atmosphere has been checked.
• Avoid smoking, naked lights or ignition sources.
• Avoid contact with incompatible materials.
• When handling, DO NOT eat, drink or smoke.
• Keep containers securely sealed when not in use.
• Avoid physical damage to containers.
• Always wash hands with soap and water after handling.
• Work clothes should be laundered separately.
• Use good occupational work practice.
• Observe manufacturer's storing and handling recommendations.
• Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.
• DO NOT allow clothing wet with material to stay in contact with skin.
SUITABLE CONTAINER
• Metal can or drums;
• Packaging as recommended by manufacturer.
• Check all containers are clearly labeled and free from leaks.
STORAGE INCOMPATIBILITY
• Avoid reaction with oxidizing agents.
STORAGE REQUIREMENTS
• Store in original containers.
• Keep containers securely sealed.
• No smoking, naked lights or ignition sources.
• Store in a cool, dry, well-ventilated area.
• Store away from incompatible materials and foodstuff containers.
• Protect containers against physical damage and check regularly for leaks.
• Observe manufacturer's storing and handling recommendations.

Transport information

Land transport (ADR/RID)

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (triphenyl phosphate)
Class:
9 Miscellaneous dangerous substances and articles
Classification code:
90
Packaging group:
III
Labels:
9
Remarks:
Not regulated for surface and air transport in non-bulk (< 119gallons) packagings. This product contains triphenyl phosphate which is a Marine Pollutant per 49 CFR 172.101, Appendix B.

Inland waterway transport (ADN(R))

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains triaryl phosphate)
Class:
9 Miscellaneous dangerous substances and articles
Classification code:
90
Packaging group:
III
Labels:
9
Remarks
Not regulated for surface and air transport in non-bulk (< 119gallons) packagings. This product contains triphenyl phosphate which is a Marine Pollutant per 49 CFR 172.101, Appendix B.

Marine transport (IMDG)

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains triaryl phosphate)
Chemical name:
Bisphenol A bis-(diphenyl phosphate)
Class:
9
Packaging group:
III
EmS code:
F-A,S-F
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3082
Proper shipping name and description:
3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID, N.O.S. (contains triaryl phosphate)
Chemical name:
Bisphenol A bis-(diphenyl phosphate)
Class:
9 Miscellaneous dangerous substances and articles
Packaging group:
III
Labels:
9
Remarks
Not regulated for surface and air transport in non-bulk (< 119gallons) packaging. This product contains triphenyl phosphate which is a Marine Pollutant per 49 CFR 172.101, Appendix B.
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Additional information about design of technical systems:
At elevated processing temperatures or in the event that use conditions generate airborne vapor, aerosol or mist, the material should be handled in a well-ventilated area.
Sufficient natural or mechanical ventilation should be provided to keep concentrations below applicable exposure limits (if limits have been established) and to help minimize exposures.
• Additional Occupational Exposure Limit Values for possible hazards during processing:
115-86-6 Triphenyl phosphate (1 - 5%)
OSHA PEL 3 mg/m³
ACGIH TLV 3 mg/m³
NIOSH TWA 3 mg/m³
• Additional information:
Due to its low vapor pressure, this product is not likely to present an inhalation hazard at normal temperatures.
At elevated temperatures, vapors and/or fumes may cause respiratory tract irritation.
• Personal protective equipment:
• General protective and hygienic measures:
The primary routes of exposure to this product are skin contact and inhalation of mists or vapors.
• Breathing equipment:
Use a NIOSH-approved organic vapor/acid gas respirator (OVAG) with dust, mist and fume filters to reduce potential for inhalation exposure if use conditions generate vapor, mist or aerosol and adequate ventilation (e.g., outdoor or well ventilated area) is not available. Where exposure necessitates a higher level of protection use a NIOSH-approved, positive pressure, pressure demand, air-supplied respirator.
• Protection of hands:
Skin contact with liquid or its aerosol should be prevented through the use of suitable protective clothing, gloves and footwear selected with regard for use condition exposure potential.
• Material of gloves Neoprene gloves
• Eye protection:
Eye contact with liquid or aerosol should be prevented through the use of chemical safety goggles and/or a face shield selected with regard for use condition exposure potential.
• Body protection:
Safety showers, with quick opening valves which stay open and eye wash fountains or other means of washing the eyes with a gentle flow of cool to tepid tap water should be readily available in all areas where this material is handled or stored. Water should be supplied through insulated and heat-traced lines to prevent freezeups in cold weather. Long sleeved clothing may be used to minimize skin contact.

Stability and reactivity

• Thermal decomposition / conditions to be avoided:
This product is stable at ambient temperatures and atmospheric pressure. It is not self-reactive and is not sensitive to static discharge or physical impact.
• Materials to be avoided:
This product is incompatible with strong oxidizers, strong acids and strong alkalis. It hydrolyzes slowly at ambient temperatures in acidic or alkaline aqueous solutions.
• Dangerous reactions Hazardous polymerization is not expected to occur.
• Dangerous products of decomposition:
Under wet alkaline or neutral conditions this product hydrolyzes slowly and nonviolently.
• Additional information: Care should be taken to prevent moisture condensation in the container.

Disposal considerations

Product:
• Recommendation:
Material that cannot be used or chemically reprocessed and empty containers, except those designed for multiple use(returnable) should be disposed of in accordance with all applicable federal, state and local regulations. Product containers for single use should be thoroughly emptied before disposal.
This product, if unused, does not meet the EPA's criteria as either a listed or characteristic hazardous waste under the Resource Conservations and Recovery Act (RCRA) as published in 40 CFR 261.

Unlearned packaging:
• Recommendation:
Containers should be drained of residual material before disposal. Emptied containers should be disposed of in accordance with all applicable laws and regulations.