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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Study period:
Between 18 August 2000 and 31 August 2000.
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Version / remarks:
Method A14 of Commission Directive 92/69/EEC (which constitutes Annex V of Council Directive 67/548/EEC).
Deviations:
not specified
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
No further details specified in the study report.
Key result
Parameter:
thermal sensitivity - Koenen test: diameter of the orifice plate
Remarks:
6mm & 2mm
Remarks on result:
negative (not further specified)
Key result
Parameter:
sensitiveness to impact: impact energy (J)
Remarks on result:
negative (not further specified)

Results

BAM fall hammer test

Test

Observations

1

There were no signs of ignition or explosion on impact. When the test assembly was dismantled there were no signs of decomposition.

2

There were no signs of ignition or explosion on impact. When the test assembly was dismantled there were no signs of decomposition.

3

There were no signs of ignition or explosion on impact. When the test assembly was dismantled there were no signs of decomposition.

4

There were no signs of ignition or explosion on impact. When the test assembly was dismantled there were no signs of decomposition.

5

There were no signs of ignition or explosion on impact. When the test assembly was dismantled there were no signs of decomposition.

6

There were no signs of ignition or explosion on impact. When the test assembly was dismantled there were no signs of decomposition.

Result: Negative

 

Koenen steel tube test

6 mm Orifice Plate

Test

Time(s)

Observations

1

87

An orange flame from the orifice.

170

The orange flame increased in size. Black smoke was emitted. Burning test material was ejected from the orifice.

249

The orange flame decreased in size.

300

The test was stopped... An orange flame remained.

The tube was recovered intact.

2

81

An orange flame from the orifice.

166

The orange flame increased in size. Black smoke was emitted. Burning test material was ejected from the orifice.

238

The orange flame decreased in size.

300

The test was stopped... An orange flame remained.

The tube was recovered intact.

3

89

An orange flame from the orifice.

175

The orange flame increased in size. Black smoke was emitted. Burning test material was ejected from the orifice.

249

The orange flame decreased in size.

300

The test was stopped... An orange flame remained.

The tube was recovered intact.

2mm Orifice Plate

Test

Time (s)

Observations

1

90

An orange flame from the orifice.

164

The orange flame increased in size. Burning test material was ejected from the orifice. Black smoke was emitted.

232

The orange flame turned to a jet orange flame.

252

The jet of orange flame reverted to an orange flame and decreased in size.

300

The test was stopped. An orange flame remained.

The tube was recovered intact.

2

81

An orange flame from the orifice.

161

The orange flame increased in size. Burning test material was ejected from the orifice. Black smoke was emitted.

226

The orange flame turned to a jet orange flame.

248

The jet of orange flame reverted to an orange flame and decreased in size.

300

The test was stopped. An orange flame remained.

The tube was recovered intact.

3

88

An orange flame from the orifice.

172

The orange flame increased in size. Burning test material was ejected from the orifice. Black smoke was emitted.

231

The orange flame turned to a jet orange flame.

250

The jet of orange flame reverted to an orange flame and decreased in size.

300

The test was stopped. An orange flame remained.

The tube was recovered intact.

Result: Negative

 

Moisture Content

 

Determination A

Determination B

a) Mass of loss bottle (g)

21.4273

19.1975

b) Mass of loss bottle and test material (g)

22.5202

20.2308

c) Mass of loss bottle and test material after drying (g)

22.5208

20.2315

Moisture content (% w/w)

<0.1

<0.1

Mean moisture content (% w/w)

<0.1

 

Interpretation of results:
GHS criteria not met
Conclusions:
The test material has been determined not to have explosive properties.
Executive summary:

The explosive properties were determined using Method A14 of Commission Directive 92/69/EEC (which constitutes Annex V of Council Directive 67/548/EEC).

 

The test material was subjected to the following:

1) The BAM fall hammer test which is a test of mechanical sensitivity with respect to shock.

2) The Koenen steel tube test which is a test of thermal sensitivity.

The BAM friction test which is not applicable to liquids, was not performed.

 

The test material has been determined not to have explosive properties.

Description of key information

The test material has been determined not to have explosive properties.

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

The explosive properties were determined using Method A14 of Commission Directive 92/69/EEC (which constitutes Annex V of Council Directive 67/548/EEC).

 

The test material was subjected to the following:

1) The BAM fall hammer test which is a test of mechanical sensitivity with respect to shock.

2) The Koenen steel tube test which is a test of thermal sensitivity.

The BAM friction test which is not applicable to liquids, was not performed.

 

The test material has been determined not to have explosive properties.

Justification for classification or non-classification

The test material has been determined not to have explosive properties and therefore does not fulfil the requirements for classification.