Registration Dossier
Registration Dossier
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EC number: 947-204-4 | CAS number: -
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
4.1 Description of first aid measures
General advice
: Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
: If unconscious, place in recovery position and get medical attention immediately.
In case of skin contact
: If on skin, rinse well with water.
If on clothes, remove clothes.
If skin irritation persists, call a physician.
Wash contaminated clothing before reuse.
In case of eye contact
: Small amounts splashed into eyes can cause irreversible tis-sue damage and blindness.
Remove contact lenses.
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Protect unharmed eye.
Keep eye wide open while rinsing.
If swallowed
: Clean mouth with water and drink afterwards plenty of water.
Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms :
Skin contact may provoke the following symptoms:
Redness
Ingestion may provoke the following symptoms:
Stomach/intestinal disorders
In case of eye contact
Excessive lachrymation
4.3 Indication of any immediate medical attention and special treatment needed
General advice
: Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
: If unconscious, place in recovery position and get medical attention immediately.
In case of skin contact
: If on skin, rinse well with water.
If on clothes, remove clothes.
If skin irritation persists, call a physician.
Wash contaminated clothing before reuse.
In case of eye contact
: Small amounts splashed into eyes can cause irreversible tis-sue damage and blindness.
Remove contact lenses.
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Protect unharmed eye.
Keep eye wide open while rinsing.
If swallowed
: Clean mouth with water and drink afterwards plenty of water.
Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms :
Skin contact may provoke the following symptoms:
Redness
Ingestion may provoke the following symptoms:
Stomach/intestinal disorders
In case of eye contact
Excessive lachrymation
4.3 Indication of any immediate medical attention and special treatment needed
Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
: Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment.
Unsuitable extinguishing media
: High volume water jet
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire-fighting
: Do not allow run-off from fire fighting to enter drains or water courses.
Hazardous combustion products
: Chlorine compounds
5.3 Advice for firefighters
Special protective equipment for firefighters
: No special protective equipment required.
Further information
: Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Suitable extinguishing media
: Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment.
Unsuitable extinguishing media
: High volume water jet
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire-fighting
: Do not allow run-off from fire fighting to enter drains or water courses.
Hazardous combustion products
: Chlorine compounds
5.3 Advice for firefighters
Special protective equipment for firefighters
: No special protective equipment required.
Further information
: Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions
:
Use personal protective equipment.
Avoid dust formation.
Avoid breathing dust.
6.2 Environmental precautions
Environmental precautions
: Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13).
6.4 Reference to other sections
Personal precautions
:
Use personal protective equipment.
Avoid dust formation.
Avoid breathing dust.
6.2 Environmental precautions
Environmental precautions
: Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13).
6.4 Reference to other sections
Handling and storage
7.1 Precautions for safe handling
Advice on safe handling
: Avoid formation of respirable particles.
Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-plication area.
Advice on protection against fire and explosion
: Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed.
Hygiene measures
: Wash hands before breaks and at the end of workday.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
: No smoking. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be care-fully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. To maintain product quality, do not store in heat or direct sun-light.
Further information on stor-age stability
: Keep in a dry place. No decomposition if stored and applied as directed.
7.3 Specific end use(s)
Advice on safe handling
: Avoid formation of respirable particles.
Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-plication area.
Advice on protection against fire and explosion
: Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed.
Hygiene measures
: Wash hands before breaks and at the end of workday.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
: No smoking. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be care-fully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. To maintain product quality, do not store in heat or direct sun-light.
Further information on stor-age stability
: Keep in a dry place. No decomposition if stored and applied as directed.
7.3 Specific end use(s)
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
8.1 Control parameters
Occupational Exposure Limits
Components CAS-No. Value type (Form of exposure) Control parameters Basis
aluminium oxide
1344-28-1
TLV 8 hr (respira-ble) 1 mg/m3
(Aluminium) BE OEL
TWA (Respirable fraction) 1 mg/m3
(Aluminium) ACGIH
calcium oxide
1305-78-8
TLV 8 hr 2 mg/m3 BE OEL
TWA (Respirable fraction) 1 mg/m3 2017/164/EU
Further information Indicative
STEL (Respirable fraction) 4 mg/m3 2017/164/EU
Further information Indicative
TWA 2 mg/m3 ACGIH
8.2 Exposure controls
Engineering measures
Handle only in a place equipped with local exhaust (or other appropriate exhaust).
Personal protective equipment
Eye protection
: Safety glasses with side-shields conforming to EN166
Hand protectionMaterial : Nitrile rubber
Break through time : > 480 min
Glove thickness : 0,12 mm
Material : PVC
Break through time : > 480 min
Glove thickness : 1,1 mm
Material : Neoprene gloves
Break through time : > 480 min
Glove thickness : 0,35 mm
Glove length : Long sleeve gloves
Skin and body protection
: Dust impervious protective suit
Respiratory protection : Suitable mask with particle filter P3 (European Norm 143)
In the case of dust or aerosol formation use respirator with an approved filter.
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
Occupational Exposure Limits
Components CAS-No. Value type (Form of exposure) Control parameters Basis
aluminium oxide
1344-28-1
TLV 8 hr (respira-ble) 1 mg/m3
(Aluminium) BE OEL
TWA (Respirable fraction) 1 mg/m3
(Aluminium) ACGIH
calcium oxide
1305-78-8
TLV 8 hr 2 mg/m3 BE OEL
TWA (Respirable fraction) 1 mg/m3 2017/164/EU
Further information Indicative
STEL (Respirable fraction) 4 mg/m3 2017/164/EU
Further information Indicative
TWA 2 mg/m3 ACGIH
8.2 Exposure controls
Engineering measures
Handle only in a place equipped with local exhaust (or other appropriate exhaust).
Personal protective equipment
Eye protection
: Safety glasses with side-shields conforming to EN166
Hand protectionMaterial : Nitrile rubber
Break through time : > 480 min
Glove thickness : 0,12 mm
Material : PVC
Break through time : > 480 min
Glove thickness : 1,1 mm
Material : Neoprene gloves
Break through time : > 480 min
Glove thickness : 0,35 mm
Glove length : Long sleeve gloves
Skin and body protection
: Dust impervious protective suit
Respiratory protection : Suitable mask with particle filter P3 (European Norm 143)
In the case of dust or aerosol formation use respirator with an approved filter.
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
Stability and reactivity
10.1 Reactivity
Stable
10.2 Chemical stability
No decomposition if stored and applied as directed.
10.3 Possibility of hazardous reactions
Hazardous reactions
: Stable under recommended storage conditions.
No hazards to be specially mentioned.
10.4 Conditions to avoid
Conditions to avoid
: None known.
No data available
10.5 Incompatible materials
Materials to avoid
: None.
10.6 Hazardous decomposition products
No decomposition if stored and applied as directed.
Stable
10.2 Chemical stability
No decomposition if stored and applied as directed.
10.3 Possibility of hazardous reactions
Hazardous reactions
: Stable under recommended storage conditions.
No hazards to be specially mentioned.
10.4 Conditions to avoid
Conditions to avoid
: None known.
No data available
10.5 Incompatible materials
Materials to avoid
: None.
10.6 Hazardous decomposition products
No decomposition if stored and applied as directed.
Disposal considerations
13.1 Waste treatment methods
Product : The product should not be allowed to enter drains, water courses or the soil.
In accordance with local and national regulations.
Do not contaminate ponds, waterways or ditches with chemi-cal or used container.
Send to a licensed waste management company.
Dispose of as hazardous waste in compliance with local and national regulations.
Dispose of in accordance with the European Directives on waste and hazardous waste.
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.
Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Product : The product should not be allowed to enter drains, water courses or the soil.
In accordance with local and national regulations.
Do not contaminate ponds, waterways or ditches with chemi-cal or used container.
Send to a licensed waste management company.
Dispose of as hazardous waste in compliance with local and national regulations.
Dispose of in accordance with the European Directives on waste and hazardous waste.
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.
Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
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