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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2013
Report date:
2013

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
GLP compliance:
yes (incl. QA statement)
Type of method:
gas saturation method

Test material

Constituent 1
Chemical structure
Reference substance name:
Chlorodiphenylphosphine
EC Number:
214-093-2
EC Name:
Chlorodiphenylphosphine
Cas Number:
1079-66-9
Molecular formula:
C12H10ClP
IUPAC Name:
diphenylphosphinous chloride
Test material form:
liquid

Results and discussion

Vapour pressureopen allclose all
Key result
Temp.:
20 °C
Vapour pressure:
0.003 hPa
Remarks on result:
other: extrapolated
Key result
Temp.:
25 °C
Vapour pressure:
0.004 hPa
Remarks on result:
other: extrapolated
Key result
Temp.:
50 °C
Vapour pressure:
0.022 hPa
Remarks on result:
other: intrapolated
Vapour pressure at 50°C (if relevant for classification of gas under pressure)
Key result
Vapour pressure:
0.022 hPa
Remarks on result:
other: intrapolated

Any other information on results incl. tables

Results:

Temperature
[°C]
Vapour Pressure
 [hPa]
Temperature
[°C]
Vapour Pressure
 [hPa]
  Saturator G   Saturator 3
56.3 0.0268 56.5 0.0325
56.2 0.0386 56.2 0.0332
41.3 0.0174* 41.4 0.0137
41.3 0.0215* 41.4 0.0171*
41.3 0.0108 41.5 0.0112
41.3 0.0132 41.3 0.0124
*: These values are not used for calculat1on of regression equation.

Vapeur pressures were calculated using a molar mass of 220.64 g/mol.

The regression of the vapour pressure data leads with a mean deviation of 9.3 % to the following results:

In (p/hPa) = 17.1677 -6784.90 / (T/K)

The vapour pressure at 20°C, 25 °C and 50°C was calculated from the regression equation.

P20°C 2.5 X 10 -3 hPa (extrapolated)

P25°C 3.7 x 10 -3 hPa (extrapolated)

P50°C 2.2 X 10 -2 hPa (interpolated)

Applicant's summary and conclusion

Conclusions:
The vapour pressure of the substance is 0.0025 hPa at 20 °C, 0.0037 hPa at 25 °C and 0,022 hPa at 50 °C.
Executive summary:

The vapour pressure of the substance is 0.0025 hPa at 20 °C, 0.0037 hPa at 25 °C and 0,022 hPa at 50 °C.