Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

Description of first aid measures

General advice :

Move out of dangerous area.

Keep at rest.

Get medical attention.

Show this safety data sheet to the doctor in attendance.

First aider needs to protect himself.

If inhaled :

If inhaled, remove to fresh air.

Keep at rest.

Consult a physician.

Skin contact : Take off all contaminated clothing immediately.

In case of skin contact:

Wash off immediately with soap and plenty of water.

Wash immediately and thoroughly for a prolonged period (at least 15 minutes).

Consult a physician.

Eye contact :

Rinse immediately with plenty of water for at least 15 minutes.

If eye irritation persists, consult a physician

Ingestion :

Do NOT induce vomiting.

Do not give anything to drink.

Get immediate medical advice/ attention.

Most important symptoms and effects, both acute and delayed:

no data available

Indication of any immediate medical attention and special treatment needed:

no data available

Fire-fighting measures

Flash point : 138 °C Method: according to a standardised method

Auto-ignition temperature : 250 °C

Flammability/Explosive limit : no data available

Extinguishing media:

Suitable extinguishing media : Dry powder;  Sand;  Carbon dioxide (CO2).

Unsuitable extinguishing media : In case of fire, never use water.

Special hazards arising from the substance or mixture:

Specific hazards during firefighting :

on heating

Corrosive or suffocating vapours are released.

Harmful or toxic vapours are released.

Advice for firefighters:

Special protective equipment for firefighters :

Special protective equipment for firefighters

In the event of fire, wear self-contained breathing apparatus.

Full protective suit

Specific fire fighting methods :

Avoid release to the environment.

Stay upwind.

Further information :

In the event of fire and/or explosion do not breathe fumes.

Use a water spray to cool fully closed containers.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:

Personal precautions, protective equipment and emergency procedures:

Avoid contact with eyes, skin and respiratory system.

Do not breathe vapour.

Use personal protective equipment.

Keep people away from and upwind of spill/leak.

Stop leak if safe to do so.

Remove all incompatible materials as quickly as possible.

Environmental precautions:

Environmental precautions:

Should not be released into the environment.

Prevent product from entering sewage system.

Contain the spilled material by bunding.

Risk Management Measures to control aqueous release:

The product should not be allowed to enter drains, water courses or the soil.

Methods and materials for containment and cleaning up:

Recovery:

Large spills should be collected mechanically (remove by pumping) for disposal.

Pump up the product into a spare container :- suitably labelled.

Acid resistant materials.

Clean-up methods - small spillage

Soak up with inert absorbent material.

Keep in suitable, closed containers for disposal.

Decontamination/cleaning : Ventilate the area.

Disposal:

Dispose of contents/ container to an approved waste disposal plant.

Dispose of in accordance with local regulations.

Handling and storage

Precautions for safe handling:

Technical measures:

Acid resisting floor

Vapour extraction at source

Advice on safe handling and usage:

Avoid all contact with water or humidity.

Keep away from metals.

Keep away from flames and hot surfaces.

Avoid the formation or spread of mists in the atmosphere.

Use only in well-ventilated areas.

Do NOT handle without gloves.

Reduce the duration of exposure to the minimum required.

Hygiene measures:

Use clean, well-maintained personal protection equipment.

Store personal protection equipment in a clean location away from the work area.

Shower or bathe at the end of working.

Wash hands before breaks and immediately after handling the product.

Remove and wash contaminated clothing and gloves, including the inside, before re-use.

Conditions for safe storage, including any incompatibilities:   Keep containers tightly closed in a dry, cool and well-ventilated

Incompatible products : Do not mix with incompatible materials.

Packaging Measures:

Packaging materials - Recommended : Store in original container.

Packaging materials - To be avoided : Aluminium, Steel drum

Storage stability:

Storage temperature : no data available

Other data : Very corrosive to metals. Hydrogen is released which forms an explosive mixture in air.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN 3265
Shipping information
Proper shipping name and description:
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (chlorodiphenylphosphine)
Chemical name:
Chlorodiphenylphosphine
Language:
English
Labels:
CORROSIVE LIQUID, ACIDIC, N.O.S
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN 3265
Shipping information
Proper shipping name and description:
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (chlorodiphenylphosphine)
Chemical name:
Chlorodiphenylphosphine
Language:
English
Labels:
CORROSIVE LIQUID, ACIDIC, N.O.S.
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
UN 3265
Shipping information
Proper shipping name and description:
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (chlorodiphenylphosphine)
Chemical name:
Chlorodiphenylphosphine
Labels:
CORROSIVE LIQUID, ACIDIC, N.O.S.
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 3265
Shippingopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters:

Contains no substances with occupational exposure limit values.

Exposure controls:

Control measures:

Engineering measures:

Avoid splashes.

Use only in well-ventilated areas.

Personal protective equipment:

Respiratory protection :

If mist is formed:

Respirator with a particle filter (EN 143)

In case of insufficient ventilation, wear suitable respiratory equipment.

Hand protection :

PVC or other plastic material gloves

Acid-resistant protective gloves.

Eye protection :

Goggles

Face-shield

Skin and body protection :

Wear suitable protective clothing, gloves and eye/face protection. impervious clothing

Boots

Hygiene measures :

Use clean, well-maintained personal protection equipment.

Store personal protection equipment in a clean location away from the work area.

Shower or bathe at the end of working.

Wash hands before breaks and immediately after handling the product.

Remove and wash contaminated clothing and gloves, including the inside, before re-use.

Protective measures :

Always have on hand a first-aid kit, together with proper instructions.

Ensure that eye flushing systems and safety showers are located close to the working place.

Environmental exposure controls:

General advice :

Should not be released into the environment.

Prevent product from entering sewage system.

Contain the spilled material by bunding.

Risk Management Measures to control aqueous release: T

he product should not be allowed to enter drains, water courses or the soil.

Stability and reactivity

Reactivity : Stable under recommended storage conditions.

Chemical stability :

Hydrolyses at room temperature on contact with humidity.

Decomposes on heating.

Possibility of hazardous reactions:       Gives off hydrogen by reaction with metals.

Conditions to avoid :   Exposure to moisture.

Incompatible materials

Materials to avoid :

Water

Bases

Strong oxidizing agents

Hazardous decomposition products:

Decomposition products :

Hydrogen chloride gas

Oxides of phosphorus

(Carbon oxides (CO + CO2)).

Disposal considerations

Waste treatment methods:

Product Disposal:

Prohibition :

Should not be released into the environment.

Do not let product enter drains.

Do not dispose of with domestic refuse.

Advice on Disposal :

Do not dispose of with domestic refuse.

Send to a licensed waste management company.

It must undergo special treatment, e.g. at suitable disposal site, to comply with local regulations.

Advice on cleaning and disposal of packaging:

Advice :

Beware of residues or vapours which remain in the drums.

Rinse with an appropriate solvent.

Allow it to drain thoroughly.

After recovery of solvent dispose of by special waste incineration.

Reason for waste disposal : Dispose of as hazardous waste in compliance with local and national regulations.