(S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate

Guidance on Safe Use

First-aid measures

Description of first aid measures

General advice:

Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.

Protection of first-aiders:

No action shall be taken involving any personal risk or without suitable training.

If inhaled:

If unconscious, place in recovery position and seek medical advice.

In case of skin contact:

Wash off with soap and plenty of water. If symptoms persist, call a physician.

In case of eye contact:

Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.

If swallowed:

Keep respiratory tract clear. Never give anything by mouth to an unconscious person.

Most important symptoms and effects, both acute and delayed

May cause an allergic skin reaction. Causes serious eye irritation.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media:

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

Specific hazards during firefighting:

Do not allow run-off from firefighting to enter drains or water courses.

Hazardous combustion products:

Carbon dioxide (CO2), Carbon monoxide, Nitrogen oxides (NOx), Sulphur oxides

Advice for firefighters

Special protective equipment for firefighters:

Wear self-contained breathing apparatus for firefighting if necessary.

Further information:

Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Personal precautions:

Use personal protective equipment. Avoid dust formation. Avoid breathing dust.

Environmental precautions

Environmental precautions:

Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.

Methods and materials for containment and cleaning up

Methods for cleaning up:

Keep in suitable, closed containers for disposal.

Handling and storage

Precautions for safe handling

Advice on safe handling:

Avoid formation of respirable particles. Do not breathe vapours/dust. Avoid contact with skin and eyes. Do not smoke. Dispose of rinse water in accordance with local and national regulations. Smoking, eating and drinking should be prohibited in the application area. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.

Advice on protection against fire and explosion:

Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed.

Hygiene measures:

When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. General industrial hygiene practice.

Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers:

Keep container tightly closed in a dry and well-ventilated

place. Electrical installations / working materials must comply with the technological safety standards. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Recommended storage temperature:

Storage class (TRGS 510)

13, Non Combustible Solids

Further information on storage stability:

Keep in a dry place.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN3077

Shipping information

Proper shipping name and description:

3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate)

Chemical name:

(S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate

Language:

English

Labels:

9

Special provisions / remarks

Special provisions:

Special marking: Symbol (fish and tree)

Inland waterway transport (UN RTDG/ADN(R))

UN number:

UN3077

Shipping information

Proper shipping name and description:

3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate)

Chemical name:

(S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate

Language:

English

Labels:

9

Special provisions / remarks

Remarks:

Special marking: Symbol (fish and tree)

Marine transport (UN RTDG/IMDG)

UN number:

UN3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate), MARINE POLLUTANT

Chemical name:

(S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate

Labels:

9

Marine pollutant

Special provisions / remarks

Remarks:

Special marking: Symbol (fish and tree)

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate)

Chemical name:

(S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate

Labels:

9

Special provisions / remarks

Remarks:

Special marking: Symbol (fish and tree)

Additional transport information

Additional information

Special provisions / remarks / other:

Special precautions for user Warning: Miscellaneous dangerous substances and articles.
· Danger code (Kemler): 90
· EMS Number: F-A,S-F
· Stowage Category A
· Stowage Code SW23
UN "Model Regulation": UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((S)-(4,5-DIHYDRO-5-THIOXO-1,3,4-THIADIAZOL-2-YL)BENZENECARBOTHIOATE), 9, III

Exposure controls / personal protection

Control parameters:

Contains no substances with occupational exposure limit values.

Exposure controls

Engineering measures

If user operations generate dust, fumes, gas, vapour or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Personal protective equipment

Eye protection:

Tightly fitting safety goggles. Wear face-shield and protective suit for abnormal processing problems.

Hand protection

Material: Nitrile rubber – NBR; Wearing time: < 60 min

Remarks:

The suitability for a specific workplace should be discussed with the producers of the protective gloves. After contamination with product change the gloves immediately and dispose of them according to relevant national and local regulations.

Skin and body protection:

Impervious clothing Dust impervious protective suit

Respiratory protection:

No personal respiratory protective equipment normally re quired.

Protective measures:

For further information, please consult the following hazardous substance information system: "GESTIS Substance Database" (German Social Accident Insurance).

Stability and reactivity

Reactivity:

No specific test data related to reactivity available for this product or its ingredients.

Chemical stability:

Stable under normal conditions.

Possibility of hazardous reactions:

Hazardous reactions:

Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid:

In the case of dusty organic products the possibility of a dust explosion should always be considered. No hazardous reactions when used as directed. Avoid release to the environment.

Incompatible materials

Materials to avoid:

No specific data.

Hazardous decomposition products:

No hazardous decomposition products are known.

Disposal considerations

Waste treatment methods

Product:

The product should not be allowed to enter drains, water courses or the soil. Send to a licensed waste management company. Do not contaminate ponds, waterways or ditches with chemical or used container.

Contaminated packaging:

Empty remaining contents. Dispose of as unused product. Do not re-use empty containers.