Amines, C12-14-alkyl, isooctyl phosphates

Flash point

Administrative data

Endpoint:

flash point of flammable liquids

Type of information:

experimental study

Adequacy of study:

key study

Study period:

The study was conducted between 26 October 2014 and 02 December 2014

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Remarks:

GLP guideline study

Data source

Reference

Reference Type:

study report

Title:

Unnamed

Year:

2015

Report date:

2015

Materials and methods

Test guideline

Test guideline 1

Qualifier:

according to guideline

Guideline:

other: Section 2.6 of Regulation (EC) No 1272/2008 of 16 December 2008 on Classification, Labelling and Packaging of Substances and Mixtures

Deviations:

no

Test guideline 2

Qualifier:

according to guideline

Guideline:

other: Section 32 of the United Nations Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria, 5th revised edition 2009

Test guideline 3

Qualifier:

according to guideline

Guideline:

EPA OPPTS 830.6315 (Flammability)

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Type of method:

closed cup

Test material

Test material information

Constituent 1

Reference substance name:

Amines, C12-14-tert-alkyl, isooctyl mono phosphates

IUPAC Name:

Amines, C12-14-tert-alkyl, isooctyl mono phosphates

Constituent 2

Reference substance name:

Unknown, including minor amounts of diphosphate species, water. Possibly residual unreacted starting material and unknown byproducts.

IUPAC Name:

Unknown, including minor amounts of diphosphate species, water. Possibly residual unreacted starting material and unknown byproducts.

Test material form:

liquid: viscous

Results and discussion

Flash point

Key result

Flash point:

95.98 °C

Atm. press.:

101.4 kPa

Any other information on results incl. tables

Results of the flash point determination are shown in the following table.

Temperature (ºC)	Observations
25.0	No flash.
30.0	No flash.
35.0	No flash.
40.0	No flash.
45.0	No flash.
50.0	No flash.
55.0	No flash.
60.0	No flash.
65.0	No flash.
70.0	No flash.
75.0	No flash.
75.0 (fresh sample)	No flash.
80.0	No flash.
85.0	No flash.
90.0	No flash.
95.0	No flash.
100.0 (fresh sample)	A blue flash spread across the sample cup.
100.0 (fresh sample)	A blue flash spread across the sample cup.
95.0 (fresh sample)	No flash.
96.0 (fresh sample)	A blue flash spread across the sample cup.
96.0 (fresh sample)	A blue flash spread across the sample cup.
94.0 (fresh sample)	No flash.
94.0 (fresh sample)	No flash.

Atmospheric pressure: 101.4 kPa

Corrected flash point: 95.98 ºC

Applicant's summary and conclusion

Conclusions:

The flash point of the test item has been determined to be 96 ± 2 °C.
The test item is not classified as a flammable liquid.

Executive summary:

The flash point has been determined to be 96 ± 2°C, using a closed cup equilibrium method designed to be compatible with Section 2.6 of Regulation (EC) No 1272/2008 of 16 December 2008 on Classification Labelling and Packaging of Substances and Mixtures, Section 32 of the United Nations Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria, 5^th revised edition 2009 and 830.6315 of US EPA Office of Chemical Safety and Pollution Prevention formerly the Office of Prevention, Pesticides and Toxic Substances (OPPTS), Series 830: Product Properties Test Guidelines. The test item is not classified as a flammable liquid.