Registration Dossier

Administrative data

First-aid measures

Inhalation
If dust from the material is inhaled, remove the affected person immediately to fresh air. Call a physician if symptoms develop or persist.

Skin contact
Wash skin with soap and water. Get medical attention if irritation develops and persists.

Eye contact
Rinse immediately with plenty of water for at least 15 minutes. Get medical attention if irritation develops and persists.

Ingestion
Rinse mouth. Get medical attention immediately.

Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media
Water. Water fog. Foam. Carbon dioxide (CO2). Dry chemical powder.

Unsuitable extinguishing media
None known.

5.2. Special hazards arising from the substance or mixture
By heating and fire, harmful vapours/gases may be formed.

5.3. Advice for firefighters

Special protective equipment for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet, gloves, rubber boots, and self-contained breathing apparatus.

Special fire fighting procedures
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. In the event of fire, cool tanks with water spray. Water runoff can cause environmental damage.

Specific methods
Cool containers exposed to flames with water until well after the fire is out.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

For non-emergency personnel
Keep unnecessary personnel away. Local authorities should be advised if significant spillages cannot be contained. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Avoid inhalation of dust from the spilled material. Wear a dust mask if dust is generated above exposure limits. Wear appropriate personal protective equipment.

For emergency responders
Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the SDS.

6.2. Environmental precautions
Avoid release to the environment.

6.3. Methods and material for containment and cleaning up
Keep combustibles (wood, paper, oil etc) away from spilled material. Collect spillage. Pick up and arrange disposal without creating dust. If sweeping of a contaminated area is necessary use a dust suppressant agent which does not react with the product. Sweep up or vacuum up spillage and
collect in suitable container for disposal. Collect dust using a vacuum cleaner equipped with HEPA filter. Prevent entry into waterways, sewer, basements or confined areas. Never return spills in original containers for re-use.

6.4. Reference to other sections
For personal protection, see section 8. For waste disposal, see section 13.

Handling and storage

7.1. Precautions for safe handling
Avoid dust formation. Do not breathe dust from this material. In case of insufficient ventilation, wear suitable respiratory equipment. Guard against dust accumulation of this material. Provide appropriate exhaust ventilation at places where dust is formed. Do not breathe mist. Avoid contact
with skin and eyes. Avoid release to the environment. Do not empty into drains. Practice good housekeeping.

7.2. Conditions for safe storage, including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. Avoid dust formation. Guard against dust accumulation of this material. Store in a cool, dry place out of direct sunlight. Keep in original container.

7.3. Specific end use(s)
Not available.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

8.1. Control parameters

Occupational exposure limits
No exposure limits noted for ingredient(s).

Biological limit values
No biological exposure limits noted for the ingredient(s).

Recommended monitoring procedures
Follow standard monitoring procedures.

Derived no-effect level (DNEL)
Not available.
Predicted no effect concentrations (PNECs)
Not available.

8.2. Exposure controls

Appropriate engineering controls
Ventilation should be sufficient to effectively remove and prevent buildup of any dusts or fumes that may be generated during handling or thermal processing. Provide eyewash station.

Individual protection measures, such as personal protective equipment

General information
Not available.

Eye/face protection
Use tight fitting goggles if dust is generated.

Skin protection
- Hand protection
Wear protective gloves.
- Other
Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Wear suitable protective clothing.

Respiratory protection
Wear respirator with dust filter. Dust Mask.

Thermal hazards
Not available.

Hygiene measures
Do not breathe dust. Avoid contact with eyes. Wash hands before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practices.

Environmental exposure controls
Contain spills and prevent releases and observe national regulations on emissions. Environmental manager must be informed of all major releases.

Stability and reactivity

10.1. Reactivity
None known.

10.2. Chemical stability
Stable at normal conditions.

10.3. Possibility of hazardous reactions
Hazardous polymerisation does not occur.

10.4. Conditions to avoid
Avoid spread of dust.

10.5. Incompatible materials
Strong oxidising agents.

10.6. Hazardous decomposition products
Thermal breakdown of this product during fire or very high heat condition may evolve the following hazardous decomposition product:
Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide.

Disposal considerations

13.1. Waste treatment methods
Residual waste
Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Local disposal regulations).

Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.

EU waste code
The Waste code should be assigned in discussion between the user, the producer and the waste disposal company.

Disposal methods/information
Incinerate. Incinerator should be appropriately equipped for silica and other fine powder which the product will generate in incineration. Workers should wear appropriate personal protective equipment(s) such as respirator. Contract with a disposal operator licensed by the Law on Disposal and Cleaning. Do not allow this material to drain into sewers/water supplies. Dispose of contents/container in accordance with local/regional/national/international regulations.