N,N''-(methylenedi-4,1-phenylene)bis[N'-octyl]urea

GHS

General Information

Name:

KY-EU

Implementation:

EU

Remarks:

- Annex VI substance (01 ATP, Index No 006-103-00-7)
- Self-reactivity: With respect to self-heating properties of the substance, it must be noted that the substance is not placed on the market as such, but as part of an oil-containing mixture. As liquids are generally not considered as self-heating according to CLP, the relevant UN test was not performed. However, to comply with REACH data requirements, an A.16 test (preliminary test) was performed with the pure substance. The result of this test was negative. In summary, the Physical hazards Classification for ‘self-heating substances and mixtures’ is considered to be conclusive.
- Corrosivity to metals: Based on the physical state of the substance (solid) and its extreme low water solubility
- Environment: The substance current classification and labelling in Annex VI in the CLP Regulation is H400 (aquatic acute 1) and H410 (aquatic chronic 1). Based on the fact that effects were observed and the substance could not be analytically detected, the EC50 was arbitrarily set by the French CA as < the water solubility limit (4.38 µg/L). However,the effects were only observed at very high loading rates (2000 and 4000 mg/L) and are most probably related to an impurity. In a repeat algae study with a WAF prepared at a loading rate of 100 mg/L no significant effects were observed. Therefore, the proposed environmental classification of the substance is H413 (aquatic chronic 4)

Related composition

Related composition:

Reaction mass of N,N’’-(methylenedi-4,1-phenylene)bis(N’-octylurea) and N,N’’-(methylenedi-4,1-phenylene)bis(N’-octadecylurea) and N-{4-[(4-{[(octadecylamino)carbonyl]amino}phenyl)methyl]phenyl}-N’-octylurea

Classification

Physical hazards

Explosives

Reason for no classification:

data conclusive but not sufficient for classification

Flammable gases and chemically unstable gases

Reason for no classification:

data conclusive but not sufficient for classification

Aerosols

Reason for no classification:

data conclusive but not sufficient for classification

Reason for no classification:

hazard class not assessed

Oxidising gases

Reason for no classification:

data conclusive but not sufficient for classification

Gases under pressure

Reason for no classification:

data conclusive but not sufficient for classification

Flammable liquids

Reason for no classification:

data conclusive but not sufficient for classification

Flammable solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-reactive substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric liquids

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-heating substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Substances and mixtures which in contact with water emit flammable gases

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising liquids

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising solids

Reason for no classification:

data conclusive but not sufficient for classification

Organic peroxides

Reason for no classification:

data conclusive but not sufficient for classification

Corrosive to metals

Reason for no classification:

data conclusive but not sufficient for classification

Desensitized explosives

Reason for no classification:

data lacking

Health hazards

Acute toxicity - oral

Reason for no classification:

data conclusive but not sufficient for classification

Acute toxicity - dermal

Reason for no classification:

data conclusive but not sufficient for classification

Acute toxicity - inhalation

Reason for no classification:

data lacking

Skin corrosion / irritation

Reason for no classification:

data conclusive but not sufficient for classification

Serious eye damage / eye irritation

Hazard category:

Eye Damage 1

Hazard statement:

H318: Causes serious eye damage.

Respiratory sensitisation

Hazard category:

Resp. Sens. 1

Hazard statement:

H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Skin sensitisation

Reason for no classification:

data conclusive but not sufficient for classification

Aspiration hazard

Reason for no classification:

data conclusive but not sufficient for classification

Reproductive toxicity

Reason for no classification:

data conclusive but not sufficient for classification

Effects on or via lactation

Reason for no classification:

data lacking

Germ cell mutagenicity

Reason for no classification:

data lacking

Carcinogenicity

Reason for no classification:

data lacking

1. Specific target organ toxicity - single (STOT-SE)

Reason for no classification:

data conclusive but not sufficient for classification

1. Specific target organ toxicity - repeated (STOT-RE)

Reason for no classification:

data conclusive but not sufficient for classification

Environmental hazards

Hazardous to the aquatic environment (acute / short-term)

Hazard category:

Aquatic Acute 1

Hazard statement:

H400: Very toxic to aquatic life.

Hazardous to the aquatic environment (long-term)

Hazard category:

Aquatic Chronic 1

Hazard statement:

H410: Very toxic to aquatic life with long lasting effects.

M-Factor acute:

100

M-Factor chronic:

100

Hazardous to the ozone layer

Reason for no classification:

data lacking

Labelling

Signal word:

Danger

Hazard pictogram

GHS05: corrosion

GHS08: health hazard

GHS09: environment

Hazard statements

H318: Causes serious eye damage.

H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements

P280: Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310: Immediately call a POISON CENTER/doctor/…

P261: Avoid breathing dust/fume/gas/mist/vapours/spray.

P285: In case of inadequate ventilation wear respiratory protection.

P304+P341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/…

P273: Avoid release to the environment.

P391: Collect spillage.

P501: Dispose of contents/container to ...

in accordance with local/regional/national/international regulations.