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Environmental fate & pathways

Hydrolysis

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Description of key information

Hydrolysis  was determined in accordance to OECD Guideline 111. The hydrolysis of PSOA was assessed in aqueous buffers at pH 4, 7 and 9 at 50 ± 0.5 °C. After 5 days PSOA was shown to have hydrolysed by considerably greater than 10% at each pH (equivalent to t0.525°C <1 year). This indicated that PSOA was hydrolytically unstable and significant hydrolysis had occurred at environmentally relevant pH.

Key value for chemical safety assessment

Additional information

Hydrolysis as a function of pH was determined in accordance to OECD Guideline 111. Standard tests for hydrolysis are not typically appropriate for the test item since PSOA is present as a complex reaction product of unknown and variable composition. However, the end-point assay of the hydrolysis test employed a spectrophotometric method for analysis of peroxycarboxylic acids. This endpoint is characterized for representative hydrocarbon structures that comprise the hydrocarbon blocks used to assess the environmental risk of this substance. The hydrolysis of PSOA was assessed in aqueous buffers at pH 4, 7 and 9 at 50 ± 0.5 °C. After 5 days PSOA was shown to have hydrolysed by considerably greater than 10% at each pH (equivalent to t0.525°C<1 year). This indicated that PSOA was hydrolytically unstable and significant hydrolysis had occurred at environmentally relevant pH.

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