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Boiling point

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Reference
Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2010-09-30 to 2010-11-09
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
OECD Guideline 103 (Boiling point/boiling range)
Version / remarks:
, 1995
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.2 (Boiling Temperature)
Version / remarks:
, 2008
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Remarks:
, signed 2010-08-25
Type of method:
differential scanning calorimetry
Key result
Boiling pt.:
267.5 °C
Atm. press.:
101.325 kPa
Decomposition:
no

Thermal stability:


Up to the final temperature of the measurement of approximately 500 °C, no exothermal effect was observed. At a temperature of 440 °C, the course of the base line indicates a pressure increase. No endothermic effect was detected during the measurements.


Boiling point:


The measured boiling temperatures were corrected to normal pressure 101.325 kPa by the following number-value equation by Sidney Young. This method can be used due to the fact that the pressure during the test differs only slightly from normal pressure 101.325 kPa (max. deviation ± 5 kPa).


Tn: T + (fT×Δp)        with Δp = (101.325−p)


p - pressure measurement in kPa


fT - temperature-correction factors for the rate of change of boiling temperature with pressure in K/kPa according to EC 440/2008


T - measured boiling temperature in K


Tn -  boiling temperature corrected to normal pressure in K


 


Normalized boiling points to 101.325 kPa









































No.



Measured boiling point / °C



Ambient pressure
/ kPa



Temperature correction factorfT/ K/kPa



Normalized boiling
point / °C



PN 301



265.45



100.43



0.433



266.84



PN303



267.66



100.43



0.435



268.05



PN305



267.31



100.34



0.435



267.74



PN307



267.06



100.17



0.434



267.56



 


The normalized boiling point of the test item at a pressure of 101.325 kPa is 267.5 °C.

Conclusions:
The boiling point of the test item at a pressure of 101.325 kPa is 267.5 °C.

Description of key information

The boiling point of the test item at a pressure of 101.325 kPa is 267.5 °C.

Key value for chemical safety assessment

Boiling point at 101 325 Pa:
267.5 °C

Additional information