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EC number: 200-431-6 | CAS number: 59-50-7
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Skin sensitisation
Administrative data
- Endpoint:
- skin sensitisation: in vivo (non-LLNA)
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- May - Sep 1979
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- comparable to guideline study with acceptable restrictions
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 1 980
- Report date:
- 1980
Materials and methods
Test guideline
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- OECD Guideline 406 (Skin Sensitisation)
- Version / remarks:
- adopted in 1992
- Deviations:
- yes
- Remarks:
- no reliability check, concentration for induction was not irritating
- GLP compliance:
- no
- Type of study:
- guinea pig maximisation test
- Justification for non-LLNA method:
- The study was conducted prior to the current requirement in Regulation (EC) 1907/2006 to perform an LLNA study (OECD 429) as the preferred in vivo skin sensitisation study.
Test material
- Reference substance name:
- Chlorocresol
- EC Number:
- 200-431-6
- EC Name:
- Chlorocresol
- Cas Number:
- 59-50-7
- Molecular formula:
- C7H7ClO
- IUPAC Name:
- 4-chloro-3-methylphenol
Constituent 1
In vivo test system
Test animals
- Species:
- guinea pig
- Strain:
- other: Pirbright White
- Sex:
- male/female
- Details on test animals and environmental conditions:
- TEST ANIMALS
- Source: Lippische Versuchstierzucht, Extertal, Germany
- Weight at study initiation: 400 g (males; first study), 300 g (females; second study)
- Housing: in Type IV Makrolon cages with dust-free wood granulate
- Diet: Altromin standard diet for guinea pigs (Altromin GmbH, Lage, Germany), twice a week
- Water: tap water, ad libitum
ENVIRONMENTAL CONDITIONS
- Temperature (°C): 22 ± 1
- Photoperiod (hrs dark / hrs light): 12 / 12
Study design: in vivo (non-LLNA)
Inductionopen allclose all
- Route:
- intradermal
- Vehicle:
- other: Lutrol 300/ethanol 3:1
- Concentration / amount:
- 25% (0.1 mL/site; first study)
1% (0.1 mL/site; second study) - Day(s)/duration:
- single injection
- Adequacy of induction:
- not specified
- Route:
- epicutaneous, occlusive
- Vehicle:
- other: Lutrol 300/ethanol 3:1
- Concentration / amount:
- 25% (first study)
1% (second study) - Day(s)/duration:
- 48 h
- Adequacy of induction:
- not specified
Challenge
- No.:
- #1
- Route:
- epicutaneous, occlusive
- Vehicle:
- other: Lutrol 300/ethanol 3:1
- Concentration / amount:
- 12.5% and 25% (first study)
25% and 50% (second study) - Day(s)/duration:
- 24 h
- Adequacy of challenge:
- other: Concentrations of 25% (1st study) and 50% (2nd study) were found to be the maximum non-irritant concentrations in an orienting test for challenge.
- No. of animals per dose:
- 15
- Details on study design:
- RANGE FINDING TESTS:
The maximum non-irritant concentration for challenge exposure was determined in orienting tests on groups of 4 untreated guinea pigs before triggering sensitization. In these tests, the substance was applied in the vehicle to various sites on the shaved flanks of each animal and left for 24 h under an occlusive dressing. The substance was applied at concentrations of 100%, 50%, 25%, and 12.5%. The 25% (fist study) and 50% (second study) suspensions were found to be the maximum non-irritant concentrations at evaluations carried out after a further 24 h and 48 h.
MAIN STUDY
A. INDUCTION EXPOSURE
- No. of exposures: 2 (intradermal and epicutaneous, respectively)
- Exposure period: single injection (intradermal) and 48 h (epicutaneous)
- Test groups:
Injection 1: Freund's complete adjuvant at 50% in water (first and second study)
Injection 2: 25% test item (first study) or 1% test item (second study) in the vehicle (Lutrol 300/ethanol 3:1)
Injection 3: 25% test item (first study) or 1% test item (second study) formulated in Freund's complete adjuvant
Epicutaneous: 25% test item (first study) or 1% test item (second study) in the vehicle (Lutrol 300/ethanol 3:1)
- Control group:
Injection 1: Freund's complete adjuvant at 50% in water (first and second study)
Injection 2: vehicle (Lutrol 300/ethanol 3:1)
Injection 3: 25% vehicle (Lutrol 300/ethanol 3:1; first study) or 1% vehicle (Lutrol 300/ethanol 3:1; second study) formulated in Freund's complete adjuvant
Epicutaneous: vehicle (Lutrol 300/ethanol 3:1)
- Site: flank on a shaven area of the back
- Frequency of applications: single injection (intradermal), single application (epicutaneous induction; one week after intradermal application)
- Duration: 9 days
- Concentrations: intradermal induction 25% (first study) or 1% (second study), epicutaneous 25% (first study) or 1% (second study)
B. CHALLENGE EXPOSURE
- No. of exposures: 1
- Day(s) of challenge: two weeks after topical induction
- Exposure period: 24 h
- Test groups: 12.5% and 25% test item (first study) or 25% and 50% test item (second study) in vehicle (Lutrol 300/ethanol 3:1)
- Control group: 12.5% and 25% test item (first study) or 25% and 50% test item (second study) in vehicle (Lutrol 300/ethanol 3:1)
- Site: left and right flanks
- Concentrations: 12.5% and 25% (first study) or 25% and 50% (second study)
- Evaluation (hr after challenge): 24 and 48 h after dressing removal - Challenge controls:
- The control group is actually a challenge control.
- Positive control substance(s):
- no
Results and discussion
In vivo (non-LLNA)
Resultsopen allclose all
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- negative control
- Dose level:
- Induction: 0%, challenge: 12.5% and 25%
- No. with + reactions:
- 0
- Total no. in group:
- 15
- Clinical observations:
- not specified
- Remarks on result:
- no indication of skin sensitisation
- Remarks:
- first study
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- negative control
- Dose level:
- Induction: 0%, challenge: 25% and 50%
- No. with + reactions:
- 0
- Total no. in group:
- 15
- Clinical observations:
- not specified
- Remarks on result:
- no indication of skin sensitisation
- Remarks:
- second study
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- test chemical
- Dose level:
- Induction: 25%, challenge: 12.5%
- No. with + reactions:
- 1
- Total no. in group:
- 15
- Clinical observations:
- not specified
- Remarks on result:
- no indication of skin sensitisation
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- test chemical
- Dose level:
- Induction: 25%, challenge: 25%
- No. with + reactions:
- 7
- Total no. in group:
- 15
- Clinical observations:
- not specified
- Remarks on result:
- positive indication of skin sensitisation
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- test chemical
- Dose level:
- Induction: 1%, challenge: 25%
- No. with + reactions:
- 0
- Total no. in group:
- 15
- Clinical observations:
- not specified
- Remarks on result:
- no indication of skin sensitisation
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- test chemical
- Dose level:
- Induction: 1%, challenge: 50%
- No. with + reactions:
- 4
- Total no. in group:
- 15
- Clinical observations:
- not specified
- Remarks on result:
- positive indication of skin sensitisation
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- negative control
- Dose level:
- Induction: 0%, challenge: 12.5%
- No. with + reactions:
- 0
- Total no. in group:
- 15
- Clinical observations:
- not specified
- Remarks on result:
- no indication of skin sensitisation
- Remarks:
- first study
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- negative control
- Dose level:
- Induction: 0%, challenge: 25%
- No. with + reactions:
- 1
- Total no. in group:
- 15
- Clinical observations:
- not specified
- Remarks on result:
- no indication of skin sensitisation
- Remarks:
- first study
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- negative control
- Dose level:
- Induction: 0%, challenge: 25% and 50%
- No. with + reactions:
- 0
- Total no. in group:
- 15
- Clinical observations:
- not specified
- Remarks on result:
- no indication of skin sensitisation
- Remarks:
- second study
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- Induction: 25%, challenge: 12.5%
- No. with + reactions:
- 3
- Total no. in group:
- 15
- Clinical observations:
- not specified
- Remarks on result:
- positive indication of skin sensitisation
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- Induction: 25%, challenge: 25%
- No. with + reactions:
- 13
- Total no. in group:
- 15
- Clinical observations:
- not specified
- Remarks on result:
- positive indication of skin sensitisation
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- Induction: 1%, challenge: 25%
- No. with + reactions:
- 0
- Total no. in group:
- 15
- Clinical observations:
- not specified
- Remarks on result:
- no indication of skin sensitisation
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- Induction: 1%, challenge: 50%
- No. with + reactions:
- 2
- Total no. in group:
- 15
- Clinical observations:
- not specified
- Remarks on result:
- positive indication of skin sensitisation
Applicant's summary and conclusion
- Interpretation of results:
- Category 1B (indication of skin sensitising potential) based on GHS criteria
- Conclusions:
- CLP: Skin Sens. 1B, H317
- Executive summary:
A study for skin sensitisation in guinea pigs was conducted with the test substance using the Magnusson-Kligman method similar to the OECD Guideline 406 (1992). Groups of 15 Pirbright White guinea pigs each were used in two parts of the study. In the first study, male animals received intradermal induction treatments consisting of three pairs of injections. The first pair of injections was of Freund's complete adjuvant (FCA) 50% diluted in water, the second pair was of 25% of the test substance in the vehicle, and the third pair of injections was of 25% of the test substance with FCA. The control group received three pairs of injections that were the same as the test group except for the absence of the test material. One week following intradermal induction an epicutaneous induction under occlusive conditions for 48 h was performed. In the test group, 25% of the test substance in vehicle was applied, while for the control group only vehicle was applied. Three weeks after the intradermal induction the animals were challenged with 25% (right flank) or 12.5% (left flank) of the test substance in vehicle under occlusive conditions for 24 h. In the second study, female animals received were induced and challenged in the same way compared to the male animals of the first study with different test substance concentrations: For the intradermal and the topical induction 1% of the test substance was applied while 25% (left flank) and 50% (right flank) were used for topical challenge. Skin reactions were evaluated at 24 and 48 h after patch removal. The Magnusson-Kligman scoring system was used to rate the skin reactions. In the first study (25% induction concentration) a skin reaction was observed in 1/15 animals (6%) after challenging with 12.5% of the test substance at 24 h and in 3/15 animals (20%) at 48 h. The application of a challenging concentration of 25% led to sensitizing effects in 7/15 males (47%) at 24 and in 13/15 animals (87%) at 48 h. In the second study (1% induction concentration) no reactions were observed after challenging with 25% the test substance at 24 and 48 h while skin reactions were noted after topical challenge with 50% test substance (4/15 females at 24 h and 2/15 females at 48 h; 27 and 13%, respectively). Thus, under the conditions of this study, the test substance is classified as Skin Sensitizer Category 1B according to Regulation (EC) No 1272/2008.
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