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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Auto flammability

Currently viewing:

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
June 29, 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2017
Report date:
2017

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Deviations:
no
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Calcium titanium trioxide
EC Number:
234-988-1
EC Name:
Calcium titanium trioxide
Cas Number:
12049-50-2
Molecular formula:
Ca.O3Ti
IUPAC Name:
Calcium titanium trioxide
impurity 1
Chemical structure
Reference substance name:
Titanium dioxide
EC Number:
236-675-5
EC Name:
Titanium dioxide
Cas Number:
13463-67-7
Molecular formula:
O2Ti
IUPAC Name:
dioxotitanium
impurity 2
Chemical structure
Reference substance name:
Silicon dioxide
EC Number:
231-545-4
EC Name:
Silicon dioxide
Cas Number:
7631-86-9
Molecular formula:
O2Si
IUPAC Name:
dioxosilane
impurity 3
impurity 4
Chemical structure
Reference substance name:
Magnesium oxide
EC Number:
215-171-9
EC Name:
Magnesium oxide
Cas Number:
1309-48-4
Molecular formula:
MgO
IUPAC Name:
magnesium oxygen(-2) anion
impurity 5
Chemical structure
Reference substance name:
Diniobium pentaoxide
EC Number:
215-213-6
EC Name:
Diniobium pentaoxide
Cas Number:
1313-96-8
Molecular formula:
Nb2O5
IUPAC Name:
diniobium pentoxide
Test material form:
solid: nanoform, surface-treated

Results and discussion

Relative self-ignition temperature (solids)
Key result
Relative self-ignition temperature:
> 400 °C
Remarks on result:
no self ignition observed under the test conditions

Any other information on results incl. tables

The test was carried out twice.

 

Run 1: No exothermic activity in the sample.

Run 2: No exothermic activity in the sample.

Applicant's summary and conclusion

Conclusions:
Following a relative self-ignition temperature for solids test, calcium titanate was shown not to undergo any exothermic reaction up to 400°C, nor to possess a relative self-ignition temperature below 400°C. Classification as an auto flammable substance is not required.
Executive summary:

An experiment was performed to determine the relative self-ignition temperature (auto flammability) of solid calcium titanate. The moisture content of the sample was 1.05 % m/m. The temperature at which the sample achieves 400°C by self-heating is termed the self-ignition temperature. The experiment was performed in duplicate. Calcium titanate did not undergo any exothermic reaction up to 400°C and did not possess a relative self-ignition temperature below 400°C. The relative self-ignition temperature for calcium titanate is >400°C. It has been concluded that classification as an auto flammable substance is not needed and that further study is not required.