Registration Dossier
Registration Dossier
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EC number: 206-496-7 | CAS number: 350-03-8
Guidance on Safe Use
Administrative data
First-aid measures
General information:
-Personal protection for the First Aider.
-Immediately remove any clothing soiled by the product.
-Take affected persons out of danger area and lay down.
-Position and transport stably in side position.
-Artificial respiration with respiration bag or respirator
After inhalation:
-Take affected persons into fresh air and keep quiet.
-Seek medical treatment.
After skin contact:
-Immediately wash with water and soap and rinse thoroughly.
-If skin irritation continues, consult a doctor.
After eye contact:
-Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
-Rinse out mouth and then drink plenty of water.
-Vomiting, possible danger of aspiration, keep breathing passages free
-Induce vomiting only, if affected person is fully conscious.
-Call a doctor immediately.
Information for doctor:
-Most important symptoms and effects, both acute and delayed : No further relevant information available.
-Indication of any immediate medical attention and special treatment needed : No further relevant information available.
Fire-fighting measures
Extinguishing media
Suitable extinguishing agents : CO2, powder or water spray. Fight larger fire with alcohol resistant foam.
Special hazards arising from the substance or mixture
-Nitrogen oxides (NOx)
-Hydrogen cyanide (HCN)
-Carbon monoxide and carbon dioxide
-Danger of forming toxic pyrolysis products.
Advice for firefighters
Protective equipment:
-Wear fully protective suit.
-Do not inhale explosion gases or combustion gases.
-Self-contained respiratory protective device.
Additional information :
-Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
-Collect contaminated fire fighting water separately. It must not enter the sewage system.
-CEFIC-ERI-Card No.: 6-03 , HIN 60
Accidental release measures
Personal precautions, protective equipment and emergency procedures
-Use respiratory protective device against the effects of fumes/dust/aerosol.
-Wear protective equipment. Keep unprotected persons away.
-Keep away from ignition sources.
-Mount respiratory protective device.
Environmental precautions : Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
-Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
-Dispose contaminated material as waste according to local / regional / national / international regulations. Details have to be arranged with the authority concerned and / or the local waste management enterprise.
Handling and storage
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Handling:
Precautions for safe handling
-Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
-Ensure good ventilation/exhaustion at the workplace.
-Prevent formation of aerosols.
Information about fire - and explosion protection: Keep ignition sources away - Do not smoke.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:
-Store only in the original receptacle.
-Provide solvent resistant, sealed floor.
Information about storage in one common storage facility:
-Do not store together with strong acids, alkalines and oxidation agents
-Store away from reducing agents.
Further information about storage conditions:
-Store in cool, dry conditions in well sealed receptacles.
-Store receptacle in a well ventilated area.
-Protect from exposure to the light.
Recommended storage temperature : At 15 °C to 25 °C
Specific end use(s) : No further relevant information available.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2810
Shipping information
- Proper shipping name and description:
- TOXIC LIQUID, ORGANIC, N.O.S. (methyl 3-pyridyl ketone)
- Chemical name:
- methyl 3-pyridyl ketone
- Language:
- English
- Labels:
- 6.1
Special provisions / remarks
- Special provisions:
- Special precautions for user Warning: Toxic substances.
Danger code (Kemler) : 60
EMS Number : F-A,S-A
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Marine transport (UN RTDG/IMDG)
- UN number:
- 2810
Shipping information
- Proper shipping name and description:
- TOXIC LIQUID, ORGANIC, N.O.S. (methyl 3-pyridyl ketone)
- Chemical name:
- methyl 3-pyridyl ketone
- Labels:
- 6.1
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 2810
Shipping information
- Proper shipping name and description:
- TOXIC LIQUID, ORGANIC, N.O.S. (methyl 3-pyridyl ketone)
- Chemical name:
- methyl 3-pyridyl ketone
- Labels:
- 6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Control parameters
Ingredients with limit values that require monitoring at the workplace : Not required
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
-Do not inhale gases / fumes / aerosols / dust
-Immediately remove all soiled and contaminated clothing
-Avoid contact with the eyes and skin
-Wash hands before breaks and at the end of work
-Store protective clothing separately.
Respiratory protection:
-Use suitable respiratory protective device in case of insufficient ventilation
-In case of brief exposure or low pollution use respiratory filter device. In case of intensive or-longer exposure use self-contained respiratory protective device
Recommended filter device for short term use : Filter A
Protection of hands : Protective gloves
Material of gloves : Butyl rubber (BR) ; Recommended material strength: ≥ 0.5 mm
Fluorocarbon rubber (Viton) ; Recommended thickness of the material: ≥ 0.4 mm
Penetration time of glove material : The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Not suitable are gloves made of the following materials:
-Natural rubber, NR
-Chloroprene rubber, CR
-Nitrile rubber, NBR
-PVC gloves
-Leather gloves
-Strong material gloves
Eye protection : Tightly sealed goggles
Stability and reactivity
Thermal decomposition / conditions to be avoided : No decomposition if used according to specifications
Possibility of hazardous reactions : Reacts with strong acids, alkalines and oxidizing agents
Conditions to avoid : No further relevant information available
Incompatible materials : No further relevant information available
Hazardous decomposition products : Nitrogen oxides (NOx)
Disposal considerations
Waste treatment methods
Recommendation : Disposal considering to the local / regional / national / international regulations. Details have to be arranged with the authority concerned and / or the local waste management enterprise
Waste disposal key : Depending on the application intended by the consumer, the allocation of waste codes according to the European waste catalogue has to be carried out in agreement with the waste disposal company and the authority
Uncleaned packaging:
Recommendation : Packagings that may not be cleansed are to be disposed of in the same manner as the product
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
