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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Immediately remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary. First aid personnel should pay attention to their own safety.

      

If inhaled:

Keep patient calm, remove to fresh air, seek medical attention. Inhale corticosteroid dose aerosol.

On skin contact:

Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

On contact with eyes:

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:

Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical attention.

Most important symptoms and effects, both acute and delayed

Further important symptoms and effects are so far not known.

Hazards: No hazard is expected under intended use and appropriate handling.

Indication of any immediate medical attention and special treatment needed

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media:

foam, water spray, dry powder

Special hazards arising from the substance or mixture

No particular hazards known.

Advice for fire-fighters

Special protective equipment:

Wear a self-contained breathing apparatus.

Further information:

Contain contaminated water/firefighting water.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Use personal protective clothing. Breathing protection required.

Environmental precautions

Do not discharge into drains/surface waters/groundwater. Do not discharge into the subsoil/soil.

Methods and material for containment and cleaning up

For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations.

For large amounts: Dike spillage. Pick up with suitable appliance and dispose of.

Handling and storage

Precautions for safe handling

Ensure thorough ventilation of stores and work areas. Avoid aerosol formation.

Protection against fire and explosion:

No special precautions necessary.

Conditions for safe storage, including any incompatibilities

Further information on storage conditions: Keep container tightly closed and dry; store in a cool place.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN2922
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Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN2922
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Marine transport (UN RTDG/IMDG)

UN number:
UN2922
Shipping information
Proper shipping name and description:
Corrosive Liquid Toxic, N.O.S (contains Acetic Acid, C..I. Basic Green 1)
Chemical name:
N-(4-{[4-(diethylamino)phenyl](phenyl)methylene}cyclohexa-2,5-dien-1-ylidene)-N-ethylethanaminium acetate
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Air transport (UN RTDG/ICAO/IATA)

UN number:
UN2922
Shipping information
Proper shipping name and description:
Corrosive Liquid Toxic, N.O.S (contains Acetic Acid, C..I. Basic Green 1)
Chemical name:
N-(4-{[4-(diethylamino)phenyl](phenyl)methylene}cyclohexa-2,5-dien-1-ylidene)-N-ethylethanaminium acetate
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Exposure controls / personal protection

Components with occupational exposure limits

CAS 64-19-7: acetic acid

TWA value 25 mg/m3 ; 10 ppm (OEL (EU))indicative

Exposure controls

Personal protective equipment

Respiratory protection:

Wear respiratory protection if ventilation is inadequate. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)

Hand protection:

Chemical resistant protective gloves (EN 374)

Suitable materials also with prolonged, direct contact (Recommended:  Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):

fluoroelastomer (FKM) - 0.7 mm coating thickness

butyl rubber (butyl) - 0.7 mm coating thickness

nitrile rubber (NBR) - 0.4 mm coating thickness

chloroprene rubber (CR) - 0.5 mm coating thickness

Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:

Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

Body protection:

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures

Do not inhale gases/vapours/aerosols. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing.

Stability and reactivity

Reactivity

No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals:

No corrosive effect on metal.

Chemical stability

The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions

No hazardous reactions if stored and handled as prescribed/indicated.

Conditions to avoid

Avoid extreme heat.

Incompatible materials

Substances to avoid:

strong oxidizing agents, strong alkalies

Hazardous decomposition products

No hazardous decomposition products if stored and handled as prescribed/indicated.

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated

Disposal considerations

Waste treatment methods

Must be disposed of or incinerated in accordance with local regulations.

Contaminated packaging:

Uncontaminated packaging can be re-used.

Packs that cannot be cleaned should be disposed of in the same manner as the contents.