Registration Dossier
Registration Dossier
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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 253-930-6 | CAS number: 38436-16-7
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
General advice : In the case of accident or if you feel unwell, seek medical advice immediately.
When symptoms persist or in all cases of doubt seek medical advice.
Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.
If inhaled : If inhaled, remove to fresh air.
If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Get medical attention immediately.
In case of skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention immediately.
Wash clothing before reuse.
Thoroughly clean shoes before reuse.
In case of eye contact : In case of contact, immediately flush eyes with plenty of wa-ter for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Get medical attention immediately.
If swallowed : If swallowed, DO NOT induce vomiting.
If vomiting occurs have person lean forward.
Call a physician or poison control centre immediately.
Rinse mouth thoroughly with water.
Never give anything by mouth to an unconscious person.
Most important symptoms and effects, both acute and delayed
Risks :Causes digestive tract burns.
Harmful if swallowed.
Causes serious eye damage.
Corrosive to the respiratory tract.
Causes severe burns.
Indication of any immediate medical attention and special treatment needed
Treatmen t: Treat symptomatically and supportively.
General advice : In the case of accident or if you feel unwell, seek medical advice immediately.
When symptoms persist or in all cases of doubt seek medical advice.
Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.
If inhaled : If inhaled, remove to fresh air.
If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Get medical attention immediately.
In case of skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention immediately.
Wash clothing before reuse.
Thoroughly clean shoes before reuse.
In case of eye contact : In case of contact, immediately flush eyes with plenty of wa-ter for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Get medical attention immediately.
If swallowed : If swallowed, DO NOT induce vomiting.
If vomiting occurs have person lean forward.
Call a physician or poison control centre immediately.
Rinse mouth thoroughly with water.
Never give anything by mouth to an unconscious person.
Most important symptoms and effects, both acute and delayed
Risks :Causes digestive tract burns.
Harmful if swallowed.
Causes serious eye damage.
Corrosive to the respiratory tract.
Causes severe burns.
Indication of any immediate medical attention and special treatment needed
Treatmen t: Treat symptomatically and supportively.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media :
Alcohol-resistant foam
Carbon dioxide (CO2)
Unsuitable extinguishing media : Dry chemical
High volume water jet
Special hazards arising from the substance or mixture
Specific hazards during fire-fighting : Do not use a solid water stream as it may scatter and spread fire.
Flash back possible over considerable distance.
Vapours may form explosive mixtures with air.
Exposure to combustion products may be a hazard to health.
Applying foam will release significant amounts of hydrogen gas that can be trapped under the foam blanket.
Applying foam initially will release significant amounts of corrosive hydrogen chloride vapors which will be reduced when uniform blanketing is achieved.
Contact with water liberates toxic gas.
Toxic vapours are evolved.
Hazardous combustion products:
Carbon oxides
Silicon oxides
Chlorine compounds
Fluorine compounds
Formaldehyde
Advice for firefighters
Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Wear neoprene gloves to prevent contact with hydrofluoric acid.
Specific extinguishing meth-ods :Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Use water spray to cool unopened containers.
Suppress (knock down) gases/vapours/mists with a water spray jet.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Remove undamaged containers from fire area if it is safe to do so.
Evacuate area.
Suitable extinguishing media :
Alcohol-resistant foam
Carbon dioxide (CO2)
Unsuitable extinguishing media : Dry chemical
High volume water jet
Special hazards arising from the substance or mixture
Specific hazards during fire-fighting : Do not use a solid water stream as it may scatter and spread fire.
Flash back possible over considerable distance.
Vapours may form explosive mixtures with air.
Exposure to combustion products may be a hazard to health.
Applying foam will release significant amounts of hydrogen gas that can be trapped under the foam blanket.
Applying foam initially will release significant amounts of corrosive hydrogen chloride vapors which will be reduced when uniform blanketing is achieved.
Contact with water liberates toxic gas.
Toxic vapours are evolved.
Hazardous combustion products:
Carbon oxides
Silicon oxides
Chlorine compounds
Fluorine compounds
Formaldehyde
Advice for firefighters
Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Wear neoprene gloves to prevent contact with hydrofluoric acid.
Specific extinguishing meth-ods :Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Use water spray to cool unopened containers.
Suppress (knock down) gases/vapours/mists with a water spray jet.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Remove undamaged containers from fire area if it is safe to do so.
Evacuate area.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions : Remove all sources of ignition.
Use personal protective equipment.
Follow safe handling advice and personal protective equipment recommendations.
Environmental precautions:
Discharge into the environment must be avoided.
Prevent further leakage or spillage if safe to do so.
Prevent spreading over a wide area (e.g. by containment or oil barriers).
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages cannot be contained.
Methods and material for containment and cleaning up
Methods for cleaning up : Non-sparking tools should be used.
Soak up with inert absorbent material.
Do not put water directly on spill however, water spray may be used to knock down the corrosive vapor cloud downwind of the spill area. Cover spill with medium expansion (>30:1) AFFF alcohol compatible foam. Do not allow foam to enter container. Applying foam initially will release significant amounts of corrosive hydrogen chloride vapors which will be reduced when uniform foam blanketing is achieved.
Flammable hydrogen gas may also be generated and trapped under the foam blanket.
For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container.
Clean up remaining materials from spill with suitable absorbent.
Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to deter-mine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
Recovered material should be stored in a vented container. The vent must prevent the ingress of water as further reaction with spilled materials can take place which could lead to overpressurization of the container.
Personal precautions : Remove all sources of ignition.
Use personal protective equipment.
Follow safe handling advice and personal protective equipment recommendations.
Environmental precautions:
Discharge into the environment must be avoided.
Prevent further leakage or spillage if safe to do so.
Prevent spreading over a wide area (e.g. by containment or oil barriers).
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages cannot be contained.
Methods and material for containment and cleaning up
Methods for cleaning up : Non-sparking tools should be used.
Soak up with inert absorbent material.
Do not put water directly on spill however, water spray may be used to knock down the corrosive vapor cloud downwind of the spill area. Cover spill with medium expansion (>30:1) AFFF alcohol compatible foam. Do not allow foam to enter container. Applying foam initially will release significant amounts of corrosive hydrogen chloride vapors which will be reduced when uniform foam blanketing is achieved.
Flammable hydrogen gas may also be generated and trapped under the foam blanket.
For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container.
Clean up remaining materials from spill with suitable absorbent.
Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to deter-mine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
Recovered material should be stored in a vented container. The vent must prevent the ingress of water as further reaction with spilled materials can take place which could lead to overpressurization of the container.
Handling and storage
Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation :Use with local exhaust ventilation.
Advice on safe handling : Do not get on skin or clothing.
Do not breathe vapours or spray mist.
Do not swallow.
Do not get in eyes.
Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment
Keep container tightly closed.
Keep away from water.
Protect from moisture.
Keep away from heat and sources of ignition.
Take precautionary measures against static discharges.
Take care to prevent spills, waste and minimize release to the environment.
Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
: Keep in properly labelled containers. Store in original container. Store in a closed container. Store locked up. Keep tightly closed. Keep in a dry place. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Product may evolve minute quantities of flammable hydrogen gas which can accumulate. Adequately ventilate to maintain vapors well below flammability limits and exposure guidelines. Do not repackage. Clogged container vents may increase pressure build up. In general chlorosilanes containing Silicon-Hydride (SiH) must be stored in pressurized packaging but some exceptions do exist. In any case the material should not be repacked without guidance from Dow Corning’s packaging experts.
Advice on common storage
:Do not store with the following product types:
Strong oxidizing agents
Organic peroxides
Explosives
Gases
Packaging material
: Unsuitable material: Do not store in or use containers except the original product package.
Specific use(s)
: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions.
For further information regarding the use of silicones / organic oils in consumer aerosol applications, please refer to the guidance document regarding the use of these type of materials in consumer aerosol applications that has been devel-oped by the silicone industry (www.SEHSC.com) or contact the Dow Corning customer service group.
Local/Total ventilation :Use with local exhaust ventilation.
Advice on safe handling : Do not get on skin or clothing.
Do not breathe vapours or spray mist.
Do not swallow.
Do not get in eyes.
Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment
Keep container tightly closed.
Keep away from water.
Protect from moisture.
Keep away from heat and sources of ignition.
Take precautionary measures against static discharges.
Take care to prevent spills, waste and minimize release to the environment.
Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
: Keep in properly labelled containers. Store in original container. Store in a closed container. Store locked up. Keep tightly closed. Keep in a dry place. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Product may evolve minute quantities of flammable hydrogen gas which can accumulate. Adequately ventilate to maintain vapors well below flammability limits and exposure guidelines. Do not repackage. Clogged container vents may increase pressure build up. In general chlorosilanes containing Silicon-Hydride (SiH) must be stored in pressurized packaging but some exceptions do exist. In any case the material should not be repacked without guidance from Dow Corning’s packaging experts.
Advice on common storage
:Do not store with the following product types:
Strong oxidizing agents
Organic peroxides
Explosives
Gases
Packaging material
: Unsuitable material: Do not store in or use containers except the original product package.
Specific use(s)
: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions.
For further information regarding the use of silicones / organic oils in consumer aerosol applications, please refer to the guidance document regarding the use of these type of materials in consumer aerosol applications that has been devel-oped by the silicone industry (www.SEHSC.com) or contact the Dow Corning customer service group.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 2987
Shipping information
- Proper shipping name and description:
- CHLOROSILANES, CORROSIVE, N.O.S.
- Language:
- English
- Labels:
- 8
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 2987
Shipping information
- Proper shipping name and description:
- CHLOROSILANES, CORROSIVE, N.O.S.
- Language:
- English
- Labels:
- 8
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 2987
Shipping information
- Proper shipping name and description:
- CHLOROSILANES, CORROSIVE, N.O.S.
- Chemical name:
- Dichloromethyl (perfluorobutylethyl) silane
- Labels:
- 8
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- Transport forbidden
Not permitted for transport
Shipping information
- Proper shipping name and description:
- Not permitted for transport
- Labels:
- Not permitted for transport
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure controls
Engineering measures
Processing may form hazardous compounds (see section 10).
Minimize workplace exposure concentrations.
Use with local exhaust ventilation.
Personal protective equipment
Eye protection:
Wear the following personal protective equipment:
Chemical resistant goggles must be worn.
If splashes are likely to occur, wear:Face-shield
Hand protection Material : Chemical-resistant gloves
Remarks:
Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Take note that the product is flammable, which may impact the selection of hand protection. Wash hands before breaks and at the end of workday.
Skin and body protection:
Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential.
Wear the following personal protective equipment:
Flame retardant antistatic protective clothing, unless assessment demonstrates that the risk of explosive atmos-pheres or flash fires is low
Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).
Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.
Filter type : Combined acidic gas/vapour and organic vapour type (AE)
Engineering measures
Processing may form hazardous compounds (see section 10).
Minimize workplace exposure concentrations.
Use with local exhaust ventilation.
Personal protective equipment
Eye protection:
Wear the following personal protective equipment:
Chemical resistant goggles must be worn.
If splashes are likely to occur, wear:Face-shield
Hand protection Material : Chemical-resistant gloves
Remarks:
Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Take note that the product is flammable, which may impact the selection of hand protection. Wash hands before breaks and at the end of workday.
Skin and body protection:
Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential.
Wear the following personal protective equipment:
Flame retardant antistatic protective clothing, unless assessment demonstrates that the risk of explosive atmos-pheres or flash fires is low
Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).
Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.
Filter type : Combined acidic gas/vapour and organic vapour type (AE)
Stability and reactivity
Reactivity
Contact with water liberates highly flammable gases.
Reacts violently with water.
Contact with water liberates toxic gas.
Chemical stability
Stable if used as directed. Follow precautionary advice and avoid incompatible materials and conditions.
Possibility of hazardous reactions
Hazardous reactions:
Combustible liquid.
Vapours may form explosive mixture with air.
Use at elevated temperatures may form highly hazardous compounds.
Can react with strong oxidizing agents.
Reacts with water.
Product may evolve flammable hydrogen gas on contact with water, alcohols, acidic or basic materials, many metals or metallic compounds and can form explosive mixtures in air.
Hazardous decomposition products will be formed upon contact with water or humid air.
Hazardous decomposition products will be formed at elevated temperatures.
Conditions to avoid
:Exposure to moisture
Heat, flames and sparks.
Incompatible materials
Materials to avoid:
Oxidizing agents
Water
Hazardous decomposition products
Contact with water or humid air : Hydrogen chloride
Thermal decomposition:
Formaldehyde
Perfluorohydrocarbons
Hydrogen fluoride
Contact with water liberates highly flammable gases.
Reacts violently with water.
Contact with water liberates toxic gas.
Chemical stability
Stable if used as directed. Follow precautionary advice and avoid incompatible materials and conditions.
Possibility of hazardous reactions
Hazardous reactions:
Combustible liquid.
Vapours may form explosive mixture with air.
Use at elevated temperatures may form highly hazardous compounds.
Can react with strong oxidizing agents.
Reacts with water.
Product may evolve flammable hydrogen gas on contact with water, alcohols, acidic or basic materials, many metals or metallic compounds and can form explosive mixtures in air.
Hazardous decomposition products will be formed upon contact with water or humid air.
Hazardous decomposition products will be formed at elevated temperatures.
Conditions to avoid
:Exposure to moisture
Heat, flames and sparks.
Incompatible materials
Materials to avoid:
Oxidizing agents
Water
Hazardous decomposition products
Contact with water or humid air : Hydrogen chloride
Thermal decomposition:
Formaldehyde
Perfluorohydrocarbons
Hydrogen fluoride
Disposal considerations
Waste treatment methods
Product : Dispose of in accordance with local regulations.
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.
Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.
Empty containers retain residue and can be dangerous.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury and/or death.
If not otherwise specified: Dispose of as unused product.
Product : Dispose of in accordance with local regulations.
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.
Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.
Empty containers retain residue and can be dangerous.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury and/or death.
If not otherwise specified: Dispose of as unused product.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
