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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Stability: thermal, sunlight, metals

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Administrative data

Link to relevant study record(s)

Description of key information

Without a polymerisation inhibitor present, liquid 4VP can autopolymerize, with potential self-heating, pressure rise and rupture of containers.  

Additional information

Commercial 4-Vinylpyridine is stabilised by the addition of a polymerisation inhibitor, such as tert-butylcatechol (1000 ppm). 4VP can undergo a self-accelerating polymerisation reaction to form poly-vinylpyridine when heated in a closed container, when water is absorbed, or when impurities are introduced to consume the stabiliser. This reaction is exothermic and can cause a significant increase in heat and pressure, which can result in splitting of the container with consequences including fire.

Justification for classification or non-classification