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Diss Factsheets

Physical & Chemical properties

Auto flammability

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
23 June 2008 to 03 July 2008
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study conducted to GLP and in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not effect the quality of the results.
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Auto-ignition temperature:
266 °C
Atm. press.:
1 006.9 - 1 019 kPa
Remarks on result:
other:

Test Temperature (ºC)

Test Volume (µl)

Ignition Delay (s)

Observations

50 (clean flask)

70

>300

No ignition

100

70

>300

No ignition

150

70

>300

No ignition.  Grey fumes were emitted

200

70

>300

No ignition.  Grey fumes were emitted

250 (clean flask)

70

>300

No ignition.  Grey fumes were emitted

300

70

>300

No ignition.  Grey fumes were emitted

350

70

5

A yellow flame.  Grey fumes were emitted

340

70

>300

No ignition.  Grey fumes were emitted

346 (clean flask)

70

1

A yellow flame.  Grey fumes were emitted

342 (clean flask)

70

1

A yellow flame.  Grey fumes were emitted

340 (clean flask)

200

1

A yellow flame.  Grey fumes were emitted

330 (clean flask)

200

>300

No ignition.  Grey fumes were emitted

336 (clean flask)

200

1

A yellow flame.  Grey fumes were emitted

332 (clean flask)

200

1

A yellow flame.  Grey fumes were emitted

330 (clean flask)

400

>300

No ignition.  Grey fumes were emitted

330 (clean flask)

600

11

A yellow flame.  Grey fumes were emitted

328 (clean flask)

600

12

A yellow flame.  Grey fumes were emitted

324 (clean flask)

600

>300

No ignition.  Grey fumes were emitted

326 (clean flask)

600

>300

No ignition.  Grey fumes were emitted

326 (clean flask)

800

>300

No ignition.  Grey fumes were emitted

326 (clean flask)

1000

1

An orange flame.  Grey fumes were emitted

324 (clean flask)

1000

1

An orange flame.  Grey fumes were emitted

322 (clean flask)

1000

1

An orange flame.  Grey fumes were emitted

318 (clean flask)

1000

1

An orange flame.  Grey fumes were emitted

310 (clean flask)

1000

1

An orange flame.  Grey fumes were emitted

302 (clean flask)

1000

1

An orange flame.  Grey fumes were emitted

294 (clean flask)

1000

1

An orange flame.  Grey fumes were emitted

286 (clean flask)

1000

18

An orange flame.  Grey fumes were emitted

278 (clean flask)

1000

>300

No ignition.  Grey fumes were emitted

282 (clean flask)

1000

>300

No ignition.  Grey fumes were emitted

284 (clean flask)

1000

>300

No ignition.  Grey fumes were emitted

284 (clean flask)

1200

>300

No ignition.  Grey fumes were emitted

284 (clean flask)

1400

147

An orange flame.  Grey fumes were emitted

282 (clean flask)

1400

>300

No ignition.  Grey fumes were emitted

282 (clean flask)

1600

154

An orange flame.  Grey fumes were emitted

280 (clean flask)

1600

>300

No ignition.  Grey fumes were emitted

280 (clean flask)

1800

209

An orange flame.  Grey fumes were emitted

278 (clean flask)

1800

236

An orange flame.  Grey fumes were emitted

276 (clean flask)

1800

>300

No ignition.  Grey fumes were emitted

276 (clean flask)

2000

>300

No ignition.  Grey fumes were emitted

276 (clean flask)

2200

254

An orange flame.  Grey fumes were emitted

274 (clean flask)

2200

>300

No ignition.  Grey fumes were emitted

274 (clean flask)

2400

>300

No ignition.  Grey fumes were emitted

274 (clean flask)

2600

247

An orange flame.  Grey fumes were emitted

272 (clean flask)

2600

>300

No ignition.  Grey fumes were emitted

272 (clean flask)

2800

>300

No ignition.  Grey fumes were emitted

272 (clean flask)

3000

213

An orange flame.  Grey fumes were emitted

270 (clean flask)

3000

>300

No ignition.  Grey fumes were emitted

270 (clean flask)

3200

>300

No ignition.  Grey fumes were emitted

270 (clean flask)

3400

263

An orange flame.  Grey fumes were emitted

268 (clean flask)

3400

289

An orange flame.  Grey fumes were emitted

266 (clean flask)

3400

>300

No ignition.  Grey fumes were emitted

266 (clean flask)

3600

207

An orange flame.  Grey fumes were emitted

264 (clean flask)

3600

>300

No ignition.  Grey fumes were emitted

264 (clean flask)

3800

>300

No ignition.  Grey fumes were emitted

264 (clean flask)

4000

>300

No ignition.  Grey fumes were emitted

264 (clean flask)

4200

>300

No ignition.  Grey fumes were emitted

264 (clean flask)

4400

>300

No ignition.  Grey fumes were emitted

Room temperature:       22 to 23°C
Atmospheric pressure: 1006.9 to 1019.0 kPa

Conclusions:
The test material has been determined to have an auto-ignition temperature of 266 ± 5°C.
Executive summary:

The auto-ignition temperature was determined by heating aliquots of the test material in a flask and observing for any ignition. Testing was conducted using Method A15 of Commision Directive 92/69/EEC (which constitutes Annex V of Council Directive 67/548/EEC).

The test material has been determined to have an auto-ignition temperature of 266 ± 5°C.

Description of key information

The test material has been determined to have an auto-ignition temperature of 266 ± 5°C.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
266 °C

Additional information

The auto-ignition temperature was determined by heating aliquots of the test material in a flask and observing for any ignition. Testing was conducted using Method A15 of Commision Directive 92/69/EEC (which constitutes Annex V of Council Directive 67/548/EEC).

The test material has been determined to have an auto-ignition temperature of 266 ± 5°C.