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Physical & Chemical properties

Vapour pressure

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Endpoint:
vapour pressure
Type of information:
read-across based on grouping of substances (category approach)
Adequacy of study:
key study
Justification for type of information:
For details on endpoint-specific justification, please see read-across justification document (category approach) in the linked category of dimethylalkylamines.
Type of method:
effusion method: vapour pressure balance
Key result
Temp.:
20 °C
Vapour pressure:
0.001 Pa
Remarks on result:
other: RA from C18-DMA
Temp.:
25 °C
Vapour pressure:
0.002 Pa
Remarks on result:
other: RA from C18-DMA
Temp.:
50 °C
Vapour pressure:
0.038 Pa
Remarks on result:
other: RA from C18-DMA

Vapour Pressure Balance (Effusion Method)

The vapour pressure was measured in the temperature range of 24 °C to 73 °C. Above 24 °C a vapour pressure could be measured. The measured vapour pressures at the corresponding temperatures are listed in the following table:

Temperature / °C

Vapour pressure / hPa

24.4

1.2× 10-5

29.5

3.2× 10-5

33.4

5.4× 10-5

39.2

1.1× 10-4

42.7

1.5× 10-4

47.2

2.8× 10-4

52.3

4.7× 10-4

56.4

7.3× 10-4

61.3

1.4× 10-3

66.6

2.3× 10-3

73.2

4.7× 10-3

The following vapour pressure values for the test item were extrapolated from the experimental data:

T / °C

p / hPa

p / Pa

20

8.9× 10-6

8.9× 10-4

25

1.8× 10-5

1.8× 10-3

50

3.8× 10-4

3.8× 10-2

Executive summary:

The study used as source investigated the vapour pressure of C18-DMA according to the effusion method (vapour pressure balance; OECD 104; EU method A.4). The study results of the source substance were considered applicable to the target substance. Justification and applicability of the read-across approach (category approach) is outlined in the read-across report in the linked category of dimethylalkylamines.

Endpoint:
vapour pressure
Type of information:
read-across based on grouping of substances (category approach)
Adequacy of study:
key study
Justification for type of information:
For details on endpoint-specific justification, please see read-across justification document (category approach) in the linked category of dimethylalkylamines.
Temp.:
20 °C
Vapour pressure:
0 hPa
Remarks on result:
other: Read-across from C16-DMA
Temp.:
25 °C
Vapour pressure:
0 hPa
Remarks on result:
other: Read-across from C16-DMA
Temp.:
50 °C
Vapour pressure:
0.004 hPa
Remarks on result:
other: Read-across from C16-DMA

Vapour Pressure (Dynamic Method):

The vapour pressure was measured with the dynamic method in the temperature range of 175 °C to 285 °C.The measured vapour pressures at the corresponding temperatures are listed in the following table:

 

Temperature / °C

Vapour pressure / hPa

175.0

9.6

202.2

30.2

212.1

50.0

234.0

99.7

245.6

150.3

264.6

299.8

284.7

499.5

222.4

69.5

193.8

20.1

The values for 20, 25 and 50 °C are calculated, using the Antoine constants A, B and C as shown here:

T / °C

p / hPa

p / Pa

20

2.0× 10-4

2.0× 10-2

25

3.4× 10-4

3.4× 10-2

50

3.6× 10-3

3.6× 10-1

Executive summary:

The study used as source investigated the vapour pressure of C16-DMA according to the dynamic method (OECD 104; EU method A.4). The study results of the source substance were considered applicable to the target substance. Justification and applicability of the read-across approach (category approach) is outlined in the read-across report in the linked category of dimethylalkylamines.

Description of key information

Vapour pressure range at 20 °C:
lower range value: 0.00089 Pa at 20 °C (source C18-DMA);
upper range value: 0.02 Pa at 20 °C (source C16-DMA).

Key value for chemical safety assessment

Vapour pressure:
0.02 Pa
at the temperature of:
20 °C

Additional information

The vapour pressure for C16-18-DMA was determined by read-across from the nearest neighbours C16-DMA (0.02 Pa at 20 °C) and C18-DMA (0.00089 Pa at 20 °C).
The highest value from the resulting range was taken as the key value.