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EC number: 231-728-9 | CAS number: 7705-07-9
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Skin sensitisation
Administrative data
- Endpoint:
- skin sensitisation: in vivo (non-LLNA)
- Type of information:
- migrated information: read-across from supporting substance (structural analogue or surrogate)
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: Meets generally accepted scientific standards, well documented. Data is suitable for read-across.
Data source
Reference
- Reference Type:
- publication
- Title:
- Evaluation of skin sensitization potential of nickel, chromium, titanium and zirconium salts using guinea-pigs and mice
- Author:
- Ikarashi Y, Momma J, Tsuchiya T, Nakamura A
- Year:
- 1 996
- Bibliographic source:
- Biomaterials 17: 2103-2108
Materials and methods
Test guideline
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- OECD Guideline 406 (Skin Sensitisation)
- Deviations:
- yes
- Remarks:
- (no data on test material purity, no range finding test was carried out prior the sensitisation test to determine the minimal irritating and maximal non-irritating concentration)
- Principles of method if other than guideline:
- The sensitisation potential of titanium tetrachloride was evaluated in the guinea pig maximization test.
- GLP compliance:
- not specified
- Type of study:
- guinea pig maximisation test
Test material
- Reference substance name:
- 7750-45-0
- Cas Number:
- 7750-45-0
- IUPAC Name:
- 7750-45-0
- Details on test material:
- - Name of test material (as cited in study report): Titanium tetrachloride, TiCl4
- Analytical purity: The test substance was obtained from Wako Pure Chemical Industries, no data on purity
Constituent 1
In vivo test system
Test animals
- Species:
- guinea pig
- Strain:
- Hartley
- Sex:
- female
- Details on test animals and environmental conditions:
- TEST ANIMALS
- Source: Japan SLC Inc.
- Weight at study initiation: 350-400 g
Study design: in vivo (non-LLNA)
Inductionopen allclose all
- Route:
- intradermal and epicutaneous
- Vehicle:
- other: saline or ethanol
- Concentration / amount:
- intradermal injection (induction): 0 and 1%; topical application (induction): 0 and 1%; challenge: 0, 2 and 5 %
Challengeopen allclose all
- Route:
- epicutaneous, occlusive
- Vehicle:
- other: saline or ethanol
- Concentration / amount:
- intradermal injection (induction): 0 and 1%; topical application (induction): 0 and 1%; challenge: 0, 2 and 5 %
- No. of animals per dose:
- Controls: 5 animals
Treated: 10 animals - Details on study design:
- In this study two independent tests were carried out to determine the sensitisation potential of the test substance.
The GPMT was performed according to the procedure described by Magnusson and Kligman (1969) with some modification. Preliminary irritation tests were carried out to determine the suitable concentrations for induction and challenge. Test guinea pigs received a series of 6 intradermal injections of the test chemical at 1% * in FCA emulsion into the shoulder region to induce sensitization. Seven days later, the animals received a 48 h occluded patch containing the chemical at the same site to boost sensitization.
The animals were challenged on flank with 20 µl of various concentrations of test chemical on the 14 days following the induction. Skin reaction was determined by visual assessment 48 h after challenge.
The intensity of the reaction was scored according to the criteria: 0 = no visible change, 1 = slight or discrete erythema, 2 = moderate and confluent erythema, 3 = intense erythema and swelling. The sensitization rate and mean skin response were also calculated. Rechallenge was performed on the 7 days after the first challenge.
* To determine the minimum induction concentration of the test chemical, one needs many animals. Therefore, an injection concentration to 1% for all chemicals was set up, and the challenge concentration was changed. In the GPMT, the minimum challenge concentration of the test substance to induce a skin response following 1% injection was 2%.
Results and discussion
In vivo (non-LLNA)
Resultsopen allclose all
- Reading:
- 1st reading
- Hours after challenge:
- 48
- Group:
- negative control
- Dose level:
- Test A: 5 %
- No. with + reactions:
- 0
- Total no. in group:
- 3
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 48.0. Group: negative control. Dose level: Test A: 5 %. No with. + reactions: 0.0. Total no. in groups: 3.0.
- Reading:
- 1st reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- Test A: 0 %
- No. with + reactions:
- 0
- Total no. in group:
- 5
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 48.0. Group: test group. Dose level: Test A: 0 %. No with. + reactions: 0.0. Total no. in groups: 5.0.
- Reading:
- rechallenge
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- Test A: 1 %
- No. with + reactions:
- 0
- Total no. in group:
- 5
- Remarks on result:
- other: Reading: rechallenge. . Hours after challenge: 48.0. Group: test group. Dose level: Test A: 1 %. No with. + reactions: 0.0. Total no. in groups: 5.0.
- Reading:
- 1st reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- Test A: 5 %
- No. with + reactions:
- 1
- Total no. in group:
- 5
- Clinical observations:
- 1 of 5 animals showed weak skin response
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 48.0. Group: test group. Dose level: Test A: 5 %. No with. + reactions: 1.0. Total no. in groups: 5.0. Clinical observations: 1 of 5 animals showed weak skin response.
- Reading:
- rechallenge
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- Test A: 2 %
- No. with + reactions:
- 3
- Total no. in group:
- 5
- Clinical observations:
- 3 of 5 animals responded after rechallenge (60 %) with stronger intensity
- Remarks on result:
- other: Reading: rechallenge. . Hours after challenge: 48.0. Group: test group. Dose level: Test A: 2 %. No with. + reactions: 3.0. Total no. in groups: 5.0. Clinical observations: 3 of 5 animals responded after rechallenge (60 %) with stronger intensity.
- Reading:
- 1st reading
- Hours after challenge:
- 48
- Group:
- negative control
- Dose level:
- Test B: 2 %
- No. with + reactions:
- 0
- Total no. in group:
- 5
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 48.0. Group: negative control. Dose level: Test B: 2 %. No with. + reactions: 0.0. Total no. in groups: 5.0.
- Reading:
- 1st reading
- Hours after challenge:
- 48
- Group:
- negative control
- Dose level:
- Test B: 5 %
- No. with + reactions:
- 0
- Total no. in group:
- 5
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 48.0. Group: negative control. Dose level: Test B: 5 %. No with. + reactions: 0.0. Total no. in groups: 5.0.
- Reading:
- 1st reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- Test B: 0 %
- No. with + reactions:
- 0
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 48.0. Group: test group. Dose level: Test B: 0 %. No with. + reactions: 0.0. Total no. in groups: 10.0.
- Reading:
- 1st reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- Test B: 2 %
- No. with + reactions:
- 1
- Total no. in group:
- 10
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 48.0. Group: test group. Dose level: Test B: 2 %. No with. + reactions: 1.0. Total no. in groups: 10.0.
- Reading:
- 1st reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- Test B: 5 %
- No. with + reactions:
- 5
- Total no. in group:
- 10
- Clinical observations:
- With regard to the results from test 1, the test substance was retested with more animals. Five of 10 (50 %) showed skin reactions by challenge.
- Remarks on result:
- other: see Remark
- Remarks:
- Reading: 1st reading. . Hours after challenge: 48.0. Group: test group. Dose level: Test B: 5 %. No with. + reactions: 5.0. Total no. in groups: 10.0. Clinical observations: With regard to the results from test 1, the test substance was retested with more animals. Five of 10 (50 %) showed skin reactions by challenge. .
Applicant's summary and conclusion
- Interpretation of results:
- sensitising
- Remarks:
- Migrated information
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