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Diss Factsheets

Physical & Chemical properties

Flash point

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2018-02-22
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Version / remarks:
2008
Deviations:
yes
Remarks:
The empty part of the flask exceeded 15% of its total capacity. This deviation was not considered to have affected the quality or the interpretation of the results obtained.
Qualifier:
according to guideline
Guideline:
ISO 3679 (Determination of flash point - Rapid equilibrium closed cup method)
Version / remarks:
March 2015
Deviations:
yes
Remarks:
The empty part of the flask exceeded 15% of its total capacity. This deviation was not considered to have affected the quality or the interpretation of the results obtained.
GLP compliance:
yes (incl. QA statement)
Type of method:
equilibrium method closed cup
Flash point apparatus:
Setaflash apparatus
Key result
Flash point:
118 °C
Atm. press.:
1 013 hPa

Preliminary test

Atmospheric pressure  97.3 kPa

Relative humidity            About 22%

 

Temperature (°C)

Flash
observation

Observed temperature
(OT)

Corrected temperature with the calibration curve (CT)

Corrected to Patm
(C)

50.7

49.0

50.0

No

60.9

59.0

60.0

No

71.1

69.0

70.0

No

81.2

79.0

80.0

No

91.3

89.0

90.0

No

101.3

99.0

100.0

No

111.3

109.0

110.0

No

121.3

119.0

120.0

Yes

116.3

114.0

115.0

No

 

The flash point was observed between 115.0°C and 120.0°C (corrected values).

 

Main test

Atmospheric pressure  97.3 kPa

Relative humidity            About 21%

 

Temperature (°C)

Flash
observation

Observed temperature
(OT)

Corrected temperature with the calibration curve (CT)

Corrected to Patm
(C)

116.3

114.0

115.0

No

117.3

115.0

116.0

No

118.3

116.0

117.0

No

119.3

117.0

118.0

Yes

 

Conclusion

The flash point of the test item was 118.0 ± 1.0°C (corrected value).

Interpretation of results:
GHS criteria not met
Conclusions:
A flash point value of 118.0 ± 1.0°C at 1013 hPa was determined for the substance using a relevant test method and in compliance with GLP. The result is considered to be reliable.

Description of key information

Flash point: 118.0 ± 1.0°C at 1013 hPa (ISO 3679)

Key value for chemical safety assessment

Flash point at 101 325 Pa:
118 °C

Additional information

A measured flash point value of 118.0 ± 1.0°C at 1013 hPa was determined for the substance using a rapid equilibrium closed-cup method in accordance with ISO 3679 Test Method and in compliance with GLP. The result is considered to be reliable and is assigned as key study.

A measured flash point value of 118.0 ± 1.0°C and a measured boiling point of 250.9 ± 2.1°C at 1013 hPa indicate that the substance should not be classified for flammability in accordance with Regulation (EC) No. 1272/2008.