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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Melting point / freezing point

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 102 (Melting point / Melting Range)
Qualifier:
according to guideline
Guideline:
EU Method A.1 (Melting / Freezing Temperature)
Qualifier:
according to guideline
Guideline:
other: EN ISO 11357-3 (Plastics-Differential scanning Calorimetry- Part 3 Determination of Temperature and enthalpy of melting and crystallization)
GLP compliance:
no
Other quality assurance:
other: EN ISO 9001
Type of method:
other: differential scanning calorimetry
Specific details on test material used for the study:
- Name of test material (as cited in study report): Hydroxypropyl methacrylate
- Physical state: liquid
- Analytical purity: 99.08%
- Lot/batch No.: 1035102305
- Storage condition of test material: between room temperature and 4 °C
Remarks on result:
other: no melting point was detected

The DSC-curve shows no melting peak in the heating cycle, but a relaxation peak and an endothermic Cp-step at – 90 °C, characteristic for a glass transition, i.e. the test item solidifies amorphously in the glassy state.

Conclusions:
No melting point was detected for hydroxypropyl methacrylate. The DSC-curve shows no melting peak in the heating cycle, but a relaxation peak and an endothermic Cp-step at – 90 °C, characteristic for a glass transition, i.e. the test item solidifies amorphously in the glassy state.
Executive summary:

The melting point of hydroxypropyl methacrylate was determined acc. OECD 102 by DSC (differential scanning) method. No melting point was detected for hydroxypropyl methacrylate. The DSC-curve shows no melting peak in the heating cycle, but a relaxation peak and an endothermic Cp-step at – 90 °C, characteristic for a glass transition, i.e. the test item solidifies amorphously in the glassy state.

Description of key information

No melting point was detected for hydroxypropyl methacrylate in a test acc. OECD 102 by differential scanning method. The DSC-curve shows no melting peak in the heating cycle, but a relaxation peak and an endothermic Cp-step at – 90 °C, characteristic for a glass transition, i.e. the test item solidifies amorphously in the glassy state.

Key value for chemical safety assessment

Melting / freezing point at 101 325 Pa:
-90 °C

Additional information

MP ca. - 90 °C