Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

- General advice:
Move out of dangerous area. Remove contaminated clothing immediately and dispose of safely.
Place and transport victim in stable position (lying sideways).

- After inhalation:
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center
immediately.

- After skin contact:
Wash off thoroughly with plenty of water and soap, if available with polyethyleneglycol 400,
subsequently rinse with water.

- After eye contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical
attention if irritation develops and persists.

- After swallowing:
Do NOT induce vomiting. Call a physician or poison control center immediately. Rinse mouth.

- Treatment
Treat symptomatically.
Gastric lavage is not normally required. If a significant amount (more than a mouthful) has been
ingested, administer activated charcoal and sodium sulphate.

Fire-fighting measures

- Suitable extinguishing agents:
water spray
carbon dioxide (CO2),
foam,
sand

- Special hazards caused by the material, its products of combustion or resulting gases:
hydrogen cyanide (hydrocyanic acid),
hydrogen fluoride,
carbon monoxide (CO),
hydrogen chloride (HCl),
nitrogen oxides (NOx)

- Protective equipment:
In the event of fire and/or explosion do not breathe fumes.
Use breathing apparatus.

- Additional information:
Contain the spread of the fire-fighting media.
Do not allow run-off from fire fighting to enter drains or water courses.

Accidental release measures

- Person-related safety precautions:
Avoid contact with spilled product or contaminated surfaces.
Wear personal protective equipment. Unprotected persons must be kept away.
Keep away sources of ignition.

- Measures for environmental protection:
Do not discharge into the drains/surface water/groundwater.

- Measures for cleaning/collecting:
Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary absorbent material).
Clean contaminated floors and objects thoroughly, observing environmental regulations.
Keep in suitable, closed containers for disposal.




Handling and storage

Manufacture and use takes place under strictly controlled conditions. The substance
is rigorously contained (production, use), appropriate risk management measures are
applied and a management system is in place. An authorisation scheme covers the
process and a procedure ensures that only trained and authorised persons handle
the substance. Process procedures for containment during cleaning and
maintenance have been accounted for in plant and engineering design as
appropriate for the site. Procedures to ensure containment have been applied for all
stages of production and processing. Occupational procedures have been assessed
and are documented.

Advice on safe handling
Use only in area provided with appropriate exhaust ventilation.

Advice on protection against fire and explosion
Keep away from heat and sources of ignition.


Storage

Requirements for storage areas and containers
Keep container tightly closed in a dry and well-ventilated place.
Store in a place accessible by authorized persons only.

Advice on common storage
Keep away from food, drink and animal feedingstuffs.

Storage stability
Storage temperature < 50 °C

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
no transport intended.
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Inland waterway transport (UN RTDG/ADN(R))

UN number:
no transport intended.
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Marine transport (UN RTDG/IMDG)

UN number:
no transport intended.
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Air transport (UN RTDG/ICAO/IATA)

UN number:
no transport intended.
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Exposure controls / personal protection

Manufacture and use takes place under strictly controlled conditions. The substance is rigorously contained (production, use), appropriate risk management measures are applied and a management system is in place. An authorisation scheme covers the process and a procedure ensures that only trained and authorised persons handle the substance. Process procedures for containment during cleaning and maintenance have been accounted for in plant and engineering design as appropriate for the site. Procedures to ensure containment have been applied for all stages of production and processing. Occupational procedures have been assessed and are documented.

Personal protective equipment:

Respiratory Protection: If product is handled while not enclosed, and if contact may occur: Full mask, Multi-range filter ABEK/P2
Hand Protection: solvent-resistant gloves, PVC or nitrile rubber gloves
Eye protection: Safety glasses with side-shields

Hygiene measures
Avoid contact with skin, eyes and clothing.
Keep working clothes separately.
Wash hands before breaks and at the end of workday.
Wash hands immediately after work, if necessary take a shower.
Remove soiled and/or soaked clothing immediately and clean thoroughly before using again.
Garments that cannot be cleaned must be destroyed (burnt).

Protective measures
If product is handled while not enclosed, and if contact may occur:
complete suit protecting against chemicals

Stability and reactivity

- Thermal decomposition:
350 °C
No decomposition up to the given temperatur.

- Hazardous Reactions:
No hazardous reactions when stored and handled according to
prescribed instructions.


Disposal considerations

During the whole life cycle of the substance all necessary measures in accordance to art. 18(4) of (EC) 1907/2006 are undertaken.
The substance is handled under strictly controlled conditions.

Waste air from the process is being burnt.
Solvents, mother liquors, solid waste is being burnt.
Waste water is treated hydrolytically under basic condition at elevated temperature and pressure.