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Diss Factsheets

Physical & Chemical properties

Explosiveness

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Administrative data

Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
Study initiation date: 1st November 2005, Study completion date: 27th March 2006
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2008
Report date:
2008

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Remarks:
Date of inspection: 12th April 2005, Date of signature: 9th June 2005

Test material

Constituent 1
Chemical structure
Reference substance name:
-
EC Number:
482-140-6
EC Name:
-
Cas Number:
13641-96-8
Molecular formula:
Hill formula: C6 H7 N O3 CAS formula: C6 H7 N O3
IUPAC Name:
2-isocyanatoethyl prop-2-enoate

Results and discussion

Small-scale preliminary testsopen allclose all
Parameter:
thermal sensitivity - Koenen test: diameter of the orifice plate
Value:
2
Remarks on result:
not thermal sensitive if heated under defined confinement
Parameter:
thermal sensitivity - Koenen test: diameter of the orifice plate
Value:
6
Remarks on result:
not thermal sensitive if heated under defined confinement
Parameter:
sensitiveness to impact: impact energy (J)
Remarks on result:
not sensitive to impact using an impact energy of 40 J

Any other information on results incl. tables

Thermal test results

T1 = time from start of test to flame from nozzle

T2 = time from start of test to explosion, or end of test (300 seconds)

   T1 (seconds)  T2 (seconds)  Observations
 6mm orifice      
 Test 1  28  300 burned with a yellow flame; tube recovered intact
 Test 2  37  300 burned with a yellow flame; tube recovered intact
 Test 3  37  300 burned with a yellow flame; tube recovered intact
       
2mm orifice      
Test 1  38  300 burned with a yellow flame; tube recovered intact
Test 2  36  300 burned with a yellow flame; tube recovered intact 
Test 3  37  300 burned with a yellow flame; tube recovered intact
          

Shock test results

N = no evidence of ignition, explosion or decomposition

 Replicate  1  2  3  4  5 6
 Result  N  N  N  N  N  N
          

Applicant's summary and conclusion

Interpretation of results:
GHS criteria not met
Conclusions:
The test material is not thermal sensitive (thermal sensitivity, effect of flame) when heated under confinement. The test materal is not sensitve to impact (mechanical sensitivity, shock) when using an impact energy of 40 J.

Based on the chemical structure the substance is not explosive according to Regulation (EC) 1272/2008 (CLP).