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Physical & Chemical properties

Auto flammability

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
The study was conducted between 30 April 2018 and 04 May 2018.
Reliability:
1 (reliable without restriction)
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
yes
Remarks:
The deviations were considered to have not affected the integrity or validity of the study.
GLP compliance:
yes
Specific details on test material used for the study:
Identification: FRET 14-0383
Appearance/Physical state: Colorless liquid
Storage conditions: Approximately 4 °C in the dark
Key result
Auto-ignition temperature:
212 °C
Atm. press.:
>= 99.7 - <= 101.7 kPa

Results of the auto-ignitiontemperaturedetermination are shown in the following table:

Temperature (ºC)

Clean Flask (Yes/No)

Volume (µL)

Ignition Delay (s)

Observations

200

Yes

70

>300

No ignition. Grey fumes were emitted.

250

Yes

70

4

An orange/blue flame. Grey fumes were emitted.

230

No

70

21

An orange/blue flame. Grey fumes were emitted.

220

No

70

>300

No ignition. Grey fumes were emitted.

226

No

70

9

An orange/blue flame. Grey fumes were emitted.

224

No

70

>300

No ignition. Grey fumes were emitted.

 

Temperature (ºC)

Clean Flask (Yes/No)

Volume (µL)

Ignition Delay (s)

Observations

224

Yes

70

21

An orange flame. Grey fumes were emitted.

222

Yes

70

>300

No ignition. Grey fumes were emitted.

222

Yes

200

23

An orange flame. Grey fumes were emitted.

220

Yes

200

19

An orange flame. Grey fumes were emitted.

218

Yes

200

9

An orange flame. Grey fumes were emitted.

216

Yes

200

10

An orange flame. Grey fumes were emitted.

214

Yes

200

>300

No ignition. Grey fumes were emitted.

214

Yes

400

>300

No ignition. Grey fumes were emitted.

214

Yes

600

>300

No ignition. Grey fumes were emitted.

214

Yes

800

>300

No ignition. Grey fumes were emitted.

214

Yes

1000

23

An orange flame. Grey fumes were emitted.

212

Yes

1000

44

An orange flame. Grey fumes were emitted.

210

Yes

1000

>300

No ignition. Grey fumes were emitted.

210

Yes

800

>300

No ignition. Grey fumes were emitted.

210

Yes

600

>300

No ignition. Grey fumes were emitted.

210

Yes

400

>300

No ignition. Grey fumes were emitted.

210

Yes

200

>300

No ignition. Grey fumes were emitted.

Room temperature:17 to 19°C
Atmospheric pressure:99.7 to 101.7kPa

Conclusions:
The substance FRET 14-0383 has a self-ignition temperature of 212 ± 5 °C according to EU Method A.15 in compliance with GLP.
Executive summary:

The substance FRET 14-0383 has a self-ignition temperature of 212 ± 5 °C according to EU Method A.15.


Description of key information

The substance FRET 14-0383 has a self-ignition temperature of 212 ± 5 °C according to EU Method A.15.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
212 °C

Additional information