Low chlorinated copper, [29H,31Hphthalocyaninato(2-)-N29,N30,N31,N32]-, wherein the number of chlorines is more than or equal to 0 and less than or equal to 7

Substance identity

Identification

Display Name:

Low chlorinated copper, [29H,31Hphthalocyaninato(2-)-N29,N30,N31,N32]-, wherein the number of chlorines is more than or equal to 0 and less than or equal to 7

EC Number:

701-372-3

Molecular formula:

C32H16CuN8, C32H15ClCuN8, C32H14Cl2CuN8, C32H13Cl3CuN8, C32H12Cl4CuN8, C32H11Cl5CuN8, C32H10Cl6CuN8, C32H9Cl7CuN8

IUPAC Name:

Low chlorinated copper, [29H,31Hphthalocyaninato(2-)-N29,N30,N31,N32]-, wherein the number of chlorines is more than or equal to 0 and less than or equal to 7

Type of Substance

Composition:

UVCB

Origin:

organometallic

Substance Identifiers

EC name

[tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

EC number

248-573-8

CAS number

27614-17-1

Trade name

29H,31H-Phthalocyanine, C,C,C,C-tetrachloro-, copper complex

29H,31H-Phthalocyanine, copper deriv.

Copper tetrachlorophthalocyanine

Copper, [C,C,C,C-tetrachloro-29H,31H-phthalocyaninato(2-)- N29,N30,N31,N32]- (9CI)

Copper, [tetrachlorophthalocyaninato(2-)]- (7CI, 8CI)

Compositions

Boundary Composition(s)

Composition 1

Nanoform

State Form:

solid: nanoform

Characterisation of nanoforms

Type of information reported:

single nanoform

Name of nanoform:

Low chlorinated copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, wherein the number of chlorines is more than or equal to 0 and less than or equal to 7_Nanoform mulimodal

Shape

Shape description

Shape description 1

Shape category:

spheroidal

Shape:

cubic

Pure shape:

no

Range:

> 1 - < 100 %

Shape description 2

Shape category:

spheroidal

Shape:

spherical

Pure shape:

no

Range:

> 1 - < 100 %

Shape description 3

Shape category:

elongated

Shape:

rod

Pure shape:

no

Range:

> 1 - < 100 %

Particle size distribution and range

Particle size distribution and range

Particle size distribution and range 1

Shape category:

spheroidal

Percentile

Percentile 1

Percentile:

D10

Range:

> 1 - < 50 nm

Percentile 2

Percentile:

D50

Range:

> 10 - < 100 nm

Percentile 3

Percentile:

D90

Range:

> 20 - < 200 nm

Fraction of constituent particles in the size range 1-100 nm:

>= 80 - < 100 %

Particle size distribution and range 2

Shape category:

elongated

Percentile

Percentile 1

Percentile:

D10

Range:

> 1 - < 100 nm

Percentile 2

Percentile:

D50

Range:

> 10 - < 300 nm

Percentile 3

Percentile:

D90

Range:

> 20 - < 500 nm

Range of length:

> 10 - < 500 nm

Range of aspect ratio (:1):

>= 3 - <= 5

Fraction of constituent particles in the size range 1-100 nm:

>= 80 - < 100 %

Crystallinity

Structures

Structure:

crystalline

Name:

Pigment 15:1

Pure structure:

yes

Specific surface area

Range of specific surface area:

> 15 - < 500 m²/g

Surface functionalisation / treatment

Surface treatment applied:

no

Legal Entity Composition(s)

Composition 2

Nanoform

State Form:

solid: nanoform

Characterisation of nanoforms

Type of information reported:

single nanoform

Name of nanoform:

Low chlorinated copper, [29H,31Hphthalocyaninato(2-)-N29,N30,N31,N32]-, wherein the number of chlorines is more than or equal to 0 and less than or equal to 7_Nanoform spheroidal

Shape

Shape description

Shape category:

spheroidal

Shape:

spherical

Pure shape:

yes

Range:

> 80 - < 100 %

Particle size distribution and range

Particle size distribution and range

Shape category:

spheroidal

Percentile

Percentile 1

Percentile:

D10

Typical value:

ca. 22.3 nm

Range:

> 1 - < 50 nm

Percentile 2

Percentile:

D50

Typical value:

ca. 46 nm

Range:

> 10 - < 55 nm

Percentile 3

Percentile:

D90

Typical value:

ca. 105.6 nm

Range:

> 50 - < 150 nm

Additional information:

analysis conducted on 643 particles

Fraction of constituent particles in the size range 1-100 nm:

ca. 88 - <= 100 %

Crystallinity

Structures

Structure:

crystalline

Name:

Pigment Blue 15:1

Pure structure:

yes

Typical composition:

ca. 100 %

Range:

> 90 - < 100 %

Description:

Powder X-Ray diffraction measurements of very fine crystals cannot be used to properly define the crystal system and Bravais lattice due to signal broadening.
(Herbst, Hunger, Industrial Organic Pigments VCH, 1993, p.44)

Specific surface area

Typical specific surface area:

ca. 17.2 m²/g

Range of specific surface area:

>= 10 - <= 80 m²/g

Surface functionalisation / treatment

Surface treatment applied:

no

low chlorinated CPC_LE

Nanoform

State Form:

solid: nanoform

Constituent 1

Reference substance name:

29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper

EC Number:

205-685-1

EC Name:

29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper

CAS Number:

147-14-8

Molecular formula:

C32H16CuN8

IUPAC Name:

[29H,31H-phthalocyaninato(2-)-kappa~2~N~29~,N~31~]copper

Constituent 2

Reference substance name:

Copper chlorophthalocyanine

EC Number:

235-476-0

EC Name:

Copper chlorophthalocyanine

CAS Number:

12239-87-1

Molecular formula:

C32H15ClCuN8

IUPAC Name:

copper chlorophthalocyanine

Constituent 3

Reference substance name:

[dichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

EC Number:

252-468-2

EC Name:

[dichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

CAS Number:

35254-77-4

Molecular formula:

C32H14Cl2CuN8

IUPAC Name:

[dichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

Constituent 4

Reference substance name:

[trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

EC Number:

249-807-1

EC Name:

[trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

CAS Number:

29719-96-8

Molecular formula:

C32H13Cl3CuN8

IUPAC Name:

[trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

Constituent 5

Reference substance name:

[tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

EC Number:

248-573-8

EC Name:

[tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

CAS Number:

27614-71-7

Molecular formula:

C32H12Cl4CuN8

IUPAC Name:

[tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

Constituent 6

Reference substance name:

[pentachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

EC Number:

263-711-7

EC Name:

[pentachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

CAS Number:

62726-15-2

Molecular formula:

C32H11Cl5CuN8

IUPAC Name:

[pentachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

Characterisation of nanoforms

Type of information reported:

single nanoform

Name of nanoform:

Low chlorinated copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, wherein the number of chlorines is more than or equal to 0 and less than or equal to 7_Nanoform mulimodal_SE-IN02

Shape

Shape description

Shape description 1

Shape category:

spheroidal

Shape:

cubic

Pure shape:

no

Range:

> 50 - < 100 %

Shape description 2

Shape category:

spheroidal

Shape:

spherical

Pure shape:

no

Range:

> 1 - < 50 %

Shape description 3

Shape category:

elongated

Shape:

rod

Pure shape:

yes

Range:

> 1 - < 20 %

Particle size distribution and range

Particle size distribution and range

Particle size distribution and range 1

Shape category:

spheroidal

Percentile

Percentile 1

Percentile:

D10

Range:

>= 0.005 - <= 0.04 μm

Percentile 2

Percentile:

D50

Range:

>= 0.01 - <= 0.06 μm

Percentile 3

Percentile:

D90

Range:

>= 0.02 - <= 0.08 μm

Fraction of constituent particles in the size range 1-100 nm:

> 80 - < 100 %

Particle size distribution and range 2

Shape category:

elongated

Percentile

Percentile 1

Percentile:

D10

Range:

>= 0.005 - <= 0.04 μm

Percentile 2

Percentile:

D50

Range:

>= 0.01 - <= 0.06 μm

Percentile 3

Percentile:

D90

Range:

>= 0.02 - <= 0.08 μm

Range of length:

> 0.01 - <= 0.2 μm

Range of aspect ratio (:1):

>= 3 - <= 5

Fraction of constituent particles in the size range 1-100 nm:

> 80 - < 100 %

Crystallinity

Structures

Structure:

crystalline

Name:

Pigment Blue 15:1

Pure structure:

yes

Specific surface area

Range of specific surface area:

>= 50 - <= 130 m²/g

Surface functionalisation / treatment

Surface treatment applied:

no

low chlorinated CPC_LE

Nanoform

State Form:

solid: nanoform

Constituent 1

Reference substance name:

29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper

EC Number:

205-685-1

EC Name:

29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper

CAS Number:

147-14-8

Molecular formula:

C32H16CuN8

IUPAC Name:

[29H,31H-phthalocyaninato(2-)-kappa~2~N~29~,N~31~]copper

Constituent 2

Reference substance name:

Copper chlorophthalocyanine

EC Number:

235-476-0

EC Name:

Copper chlorophthalocyanine

CAS Number:

12239-87-1

Molecular formula:

C32H15ClCuN8

IUPAC Name:

copper chlorophthalocyanine

Constituent 3

Reference substance name:

[dichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

EC Number:

252-468-2

EC Name:

[dichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

CAS Number:

35254-77-4

Molecular formula:

C32H14Cl2CuN8

IUPAC Name:

[dichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

Constituent 4

Reference substance name:

[trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

EC Number:

249-807-1

EC Name:

[trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

CAS Number:

29719-96-8

Molecular formula:

C32H13Cl3CuN8

IUPAC Name:

[trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

Constituent 5

Reference substance name:

[tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

EC Number:

248-573-8

EC Name:

[tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

CAS Number:

27614-71-7

Molecular formula:

C32H12Cl4CuN8

IUPAC Name:

[tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

Constituent 6