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Environmental fate & pathways

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Description of key information

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ENVIRONMENTAL FATE PROPERTIES


Summary of degradation


Mn is inorganic and hence the ready biodegradation and hydrolysis tests are not relevant. This is because there is no carbon to be evolved and no chemical bonds to be broken, respectively. The water solubility of Mn is 0.7 mg/l at 20°C and a transformation dissolution study has shown that the concentration of manganese dissolved and/or transformed is 585.6 µg/l after 7 days from 1mg/L loading (i.e the water solubility). Not surprisingly these limit values are rather higher than the background concentration of manganese in European environments (15.9 µg Mn/L in surface water, 452 mg/kg in sediment, 428.6 mg/kg in soil; “Probabilistic Distribution of Manganese in European Surface Water, Sediment and Soil and Derivation of Predicted Environmental Concentrations (PEC)”, Parametrix, 2009 and supported by GEMAS data).


Volatilisation


Data on volatilisation are not available for the substance. Mn is a solid and hence not volatile.


Distribution modelling


No distribution modelling data exist.


Summary of environmental distribution


 


The 72hr adsorption/desorption study (OECD 106) on MnCl2 (a more soluble/readily available form of Manganese (Mn2+)) in 35 different soil types illustrate that adsorption is pH sensitive. A median Kd of 994 ml/g was determined for all soil types used (pH range 3.0-8.5


 


Summary and discussion of bioaccumulation


Manganese is an essential trace nutrient in animals and is required for the photosynthetic process in plants. Hence unacceptable bioaccumulation is highly unlikely to occur in any organism due to their ability to regulate intake and loss from natural sources.


Secondary poisoning


Bioaccumulation of Mn is not expected to occur. Hence no secondary poisoning risk exists.


Assessment of PBT/vPvB Properties - Comparison with the Criteria of Annex XIII


According to the Guidance on information requirements and chemical safety assessment, Chapter R.11: PBT assessment, “the PBT and vPvB criteria of Annex XIII to the regulation do not apply to inorganic substances”. Therefore Mn metal is not considered to require any further assessment of PBT properties