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Physical & Chemical properties

Melting point / freezing point

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Administrative data

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Reference
Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2003
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
EU Method A.1 (Melting / Freezing Temperature)
Deviations:
not specified
GLP compliance:
yes
Type of method:
thermal analysis
Key result
Decomposition:
yes
Decomp. temp.:
> 100 °C

No melting point can be defined in the range 25 - 1000 °C due to the decomposition of the substance. If heated above 100 °C water is lost and boric acid converts initially to metaboric acid (HBO2) and on further heating forms boric oxide (B2O3)

Conclusions:
No melting point can be defined in the range 25 - 1000 °C due to the decomposition of the substance above 100 °C.
Executive summary:

The melting point of the test substance was determined with Differential Thermal Analysis according to EU Method A.1 and GLP. No melting point can be defined in the range 25 - 1000 °C due to the decomposition of the substance above 100 °C. If heated above 100 °C water is lost and boric acid converts initially to metaboric acid (HBO2) and on further heating forms boric oxide (B2O3).

Description of key information

The melting point of the test substance was determined with Differential Thermal Analysis according to EU Method A.1 and GLP. No melting point can be defined in the range 25 - 1000 °C due to the decomposition of the substance above 100 °C. If heated above 100 °C water is lost and boric acid converts initially to metaboric acid (HBO2) and on further heating forms boric oxide (B2O3).

This result is supported by textbook-data (Kirk-Othmer Encyclopedia of Chemical Technology) which show the same results.

Key value for chemical safety assessment

Additional information