Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Endpoint summary

Administrative data

Description of key information

Citric acid is a solid at standard temperature and pressure, with a melting point of 153°C at 1013 hPa. The substance does not have a boiling point due to decomposition from >175°C. It has a relative density of 1.665 at 20°C and a vapour pressure of 2.2E-6 Pa at 25°C.

The substance is not classified for flammability according to Regulation (EC) No. 1272/2008 on the basis of a burning test study conducted in accordance with a relevant test method. No measured relative self-ignition temperature is available due to the melting point being lower than 160°C. It is not explosive and not oxidising on the basis of chemical structure.

Citric acid is highly soluble in water (592 g/L at 20°C). In aqueous solution, citric acid is expected to be at least partly ionised at all relevant environmental pH, with acid dissociation constants, pKa, of 3.13, 4.76 and 6.4 at 25°C. It has a very low log Kow value of -1.6 to -4 at pH 7.

For citric acid, the fraction below 100 µm was 84.1% and the D50 of the fraction below 100 µm was at 31.99 µm.

Additional information