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EC number: 300-212-6 | CAS number: 93924-19-7 Hollow ceramic spheres formed as a part of the ash in power stations burning pulverized coal. Composed primarily of the oxides of aluminium, iron and silicon and contain carbon dioxide and nitrogen within the sphere.
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data

Bioaccumulation: aquatic / sediment
Administrative data
Link to relevant study record(s)
Description of key information
The bioaccumulation potential of cenospheres is low.
Key value for chemical safety assessment
Additional information
No bioaccumulation study is available for the cenospheres, but it can be concluded that cenospheres are not bioavailable for aquatic organisms due to its physical and chemicals properties as inert, hollow balls of sand-like material; Thus considering the extremely low recovery rate of ash contents, experienced from toxicological investigations and based on the structure-related properties of the substance, bioavailability and therefore bioconcentration of cenospheres contents is not expected.
The Tennessee Valley Authority (TVA) initiated two-phase laboratory sediment and surface water toxicity studies in the spring and summer of 2009. The objective of this testing was to determine whether constituents associated with fly ash including cenospheres found in site sediment and surface water are harmful to or are bio-accumulated by benthic invertebrates. The primary focus of the initial studies was on the potential for short-term effects associated with removing ash from the. The toxic effects endpoints measured include survival, growth and reproduction, and metals bioaccumulation elicited by exposure of benthic and aquatic species to whole ash, ash elutriates, dredge plume water, and ash stilling pond effluent. The results from these „A Multi-phased Toxicity Study for Evaluating Potential Risks of Kingston Fossil Plant Fly Ash Exposure to Benthic and Aquatic Biota“ ash composite samples indicated no appreciable bioaccumulation of metals in Corbicula fluminea exposures (28-d) to whole ash (R. Sherrard; poster, SETAC, 2009). The Bioaccumulation Factors (BAFs) are negligible, all BAF values for the measured heavy metals are below 1; the maximum BAF among metals was for zinc (mean = 0.343, range = 0.146 - 0.591 kg sediment (dry wt) / kg body weight (wet wt).
A second 4-day Lumbriculus variegatus toxicity test (pre-bioaccumulation test) shows also no significant difference between resin-treated ash and lab control and criteria for conducting 28-day bioaccumulation test were not met (R. Sherrard; Poster, SETAC, 2009 and Hydrosphere Research, 2009) and also in a field study with fish was no indication for a bioaccumulation potential of the fly ash including cenospheres. There were differences between sites in some indicators of exposure and effects in these fish collected 2-3 months after the spill, there were no consistent relationships between metal bioaccumulation and indicator responses and female fish collected at and downstream of the spill in spring/summer 2009 had no obvious significant reproductive abnormalities.
It can be therefore concluded that a significant bioaccumulation of ash contents including cenospheres is not expected and further bioaccumulation studies are not necessary.
Reference: R. Sherrard – Tennessee Valley Authority, Kingston Ash Recovery Project, Kingston, TN and Hydrosphere Research, 11842 Research Circle, Alachua, FL 32615, Ph. 386-462-7889 cited from: SETAC POSTER 2009 and: http://www.tva.gov/)
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