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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flammability

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Administrative data

Link to relevant study record(s)

Description of key information

Sodium is a hydrolytically unstable substance and on contact with moisture it becomes sodium hydroxide and hydrogen.  Sodium is WATER-REACTIVE (EMITTING FLAMMABLE GASES)

Key value for chemical safety assessment

Flammability:
contact with water liberates highly flammable gases

Additional information

Flammability in contact with water: sodium is hydrolytically unstable and in contact with moisture, it becomes sodium hydroxide and hydrogen. Hydrogen has explosive properties.

  • According to US department on Transportation (2004), sodium is WATER-REACTIVE (EMITTING FLAMMABLE GASES)/ Fire or Explosion: Produce flammable gases on contact with water. May ignite on contact with water or moist air.
  • According to EU classification (67/548/EEC) sodium is classified F: Flammable; R14/15: reacts violently with water, liberating extremely flammable gases
  • According to CLP classification (1272/2008/CEE), sodium is classified Water React. 1: substance which in contact with water emits flammable gases; H260: in contact with water releases flammable gases which may ignite spontaneously gases which may ignite spontaneously

Justification for classification or non-classification

Sodium is listed on Annex VI of regulation n°1272/2008 of 16 December 2008 with R14/15 (F) and H260 (water react. 1) classification (" Reacts violently with water, liberating extremely flammable gases").

No change to this classification is proposed.