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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

4.1. Description of first aid measures


 


General advice


Medical treatment is necessary if symptoms are evidently caused by effects of the product on the skin, eyes or respiratory system. Remove contaminated, soaked clothing.


 


Inhalation       Move subject to fresh air and keep him calm. In case of complaints get medical advice.


 


Skin contact


Wash off immediately with soap and water. If skin irritation persists, call a physician.


 


Eye contact


Flush eyes thoroughly with water.


 


Ingestion


Do not induce vomiting. Get medical advice immediately.


 


 


4.2. Most important symptoms and effects, both acute and delayed


 


Product has dermal defatting effect, May cause eye/skin irritation.


 


 


4.3. Indication of any immediate medical attention and special treatment needed


no

Fire-fighting measures

5.1. Extinguishing media


 


Suitable extinguishing media


dry chemical, carbon dioxide, foam


 


Extinguishing media which must not be used for safety reasons


water  


 


5.2. Special hazards arising from the substance or mixture


 


May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.


 


5.3. Advice for firefighters


 


Wear self-contained breathing apparatus.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


 


Ensure sufficient ventilation. Use personal protective clothing. Keep away sources of ignition. Use breathing apparatus if exposed to vapours/dust/mist/aerosol.


 


6.2. Environmental precautions


 


Prevent product from getting into subsoil/soil. Prevent product from getting into drains/surface water/groundwater.


 


6.3. Methods and material for containment and cleaning up


 


Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment! Smaller quantities and/or residues: Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust). Dispose of in accordance with regulations.


 


6.4. Reference to other sections


 


For personal protection see section 8.

Handling and storage

Safe handling advice


Keep container tightly closed. Ensure there is good room ventilation. Take precautionary measures against static discharge.


 


Advice on protection against fire and explosion       


When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air. In the event of fire, cool the endangered containers with water. Keep away from sources of ignition


 


7.2. Conditions for safe storage, including any incompatibilities


 


Requirements for storage areas and containers


Keep only in the original container at a temperature not exceeding 30 °C. Protect from the action of light. Fill the container by approximately 90 % only as oxygen (air) is required for stabilisation. With large storage containers make sure the oxygen (air) supply is sufficient to ensure stability. Can polymerize with intense heat release.


 


7.3. Specific end use(s)


 


no

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
3077
Shipping information
Proper shipping name and description:
UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains Behenyl acrylate), 9, III, (E)
Hazard no. 90
Chemical name:
Behnenyl acrylate
Language:
English
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
3077
Shipping information
Proper shipping name and description:
UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains Behenyl acrylate), 9, III, (E)
Hazard no. 90
Chemical name:
Behenyl acrylate
Language:
English
Labels:
9
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
3077
Shipping information
Proper shipping name and description:
UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains Behenyl acrylate), 9, III, (E)
Hazard no. 90
Chemical name:
Behenyl acrylate
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
3077
Shipping information
Proper shipping name and description:
UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains Behenyl acrylate), 9, III, (E)
Hazard no. 90
Chemical name:
Behenyl acrylate
Labels:
9
Special provisions / remarks
Remarks:
Per 49 CFR 172.101 Appendix B, DOT does state that if a material is not a DOT marine pollutant but meets the definition of an environmentally hazardous substance (aquatic environment) in IMDG Code 2.9.3, it may be offered for transport and transported as a marine pollutant.
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1. Control parameters


 


 


8.2. Exposure controls


 


For monitoring procedures refer for instance to "Empfohlene Analysenverfahren für Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health


 


Protective measures


Do not breathe vapours. Avoid contact with eyes and skin.


 


Hygiene measures


Take off all contaminated clothing immediately. Follow the usual good standards of occupational hygiene. Store work clothing separately. Use skin protective preparation as preventive skin protection.


 


Respiratory protection


not required on normal handling


 


Hand protection       


nitrile rubber gloves (minimal thickness 0.33 mm), Break through time > 10 min (EN 374)       butyl rubber gloves (minimal thickness 0.7 mm), Break through time > 30 min (EN 374)


In practice, due to variable exposure conditions, this information can only be an aid to orientation for the selection of a suitable chemical protection glove. In particular, this information does not substitute suitability tests by the end user.


 


Splash protection       


neoprene gloves


nitrile rubber gloves


 


 


General information       


Gloves should be replaced regularly, especially after extended contact with the product. For each work-place a suitable glove type has to be selected.


 


Eye protection       


tightly fitting safety goggles

Stability and reactivity

10.1. Reactivity


 


see section 10.2.


 


10.2. Chemical Stability


 


No decomposition if stored and applied as directed.


 


Depolymerization begins at 200 °C


 


 


10.3. Possibility of hazardous reactions


 


Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions.


UV light causes radical polymerization.


 


 


10.4. Conditions to avoid


 


High temperature.Ultraviolet light.Keep away from direct sunlight.


 


 


10.5. Incompatible materials


 


Radical producers such as peroxides


Reducing agents.


Tertiary amines.


Heavy metals.


oxidizing agents


Mineral acids.


 


 


10.6. Hazardous decomposition products


 


None when used as directed.

Disposal considerations

13.1. Waste treatment methods


 


Product


Waste is non-hazardous. It should be disposed of in accordance with the regulations after consultation of the competent local authorities and the disposal company in a suitable and licensed facility.


 


Uncleaned packaging


Contaminated packaging should ideally be emptied; it can then be recycled after having been decontaminated. Packaging which cannot be decontaminated should be disposed of like the material. Packaging that cannot be cleaned should be disposed of professionally. Uncontaminated packaging may be taken for recycling.


 


Code of waste EWC


13 02 05


waste engine, gear and lubricating oils - mineral-based non-chlorinated engine, gear and lubricating oils


 


Always check the given waste codes according to the actual conditions of manufacturing, formulation or use in your facilities.