Silicic acid (H4SiO4), tetraethyl ester, reaction products with bis(acetyloxy)dibutylstannane

GHS

General Information

Implementation:

EU

Type of classification:

self-classification

Remarks:

CMR and STOT classification of the UVCB substance CAS 93925-42-9 refer to the classification of dibutyltin diacetate (CAS 1067 -33 -0). The given SCLs are a correction for the tin content in CAS 93925-42-9 relative to that of dibutyltin diacetate.

Related composition

Related composition:

Silicic acid (H4SiO4), tetraethyl ester, reaction products with bis(acetyloxy)dibutylstannane

Classification

Physical hazards

Explosives

Reason for no classification:

data conclusive but not sufficient for classification

Flammable gases and chemically unstable gases

Reason for no classification:

data conclusive but not sufficient for classification

Aerosols

Reason for no classification:

data conclusive but not sufficient for classification

Reason for no classification:

hazard class not assessed

Oxidising gases

Reason for no classification:

data conclusive but not sufficient for classification

Gases under pressure

Reason for no classification:

data conclusive but not sufficient for classification

Flammable liquids

Hazard category:

Flam. Liquid 3

Hazard statement:

H226: Flammable liquid and vapour.

Flammable solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-reactive substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric liquids

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-heating substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Substances and mixtures which in contact with water emit flammable gases

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising liquids

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising solids

Reason for no classification:

data conclusive but not sufficient for classification

Organic peroxides

Reason for no classification:

data conclusive but not sufficient for classification

Corrosive to metals

Reason for no classification:

data conclusive but not sufficient for classification

Desensitized explosives

Reason for no classification:

data lacking

Health hazards

Acute toxicity - oral

Hazard category:

Acute Tox. 4

Hazard statement:

H302: Harmful if swallowed.

Acute toxicity - dermal

Reason for no classification:

data lacking

Acute toxicity - inhalation

Hazard category:

Acute Tox. 4

Hazard statement:

H332: Harmful if inhaled.

Skin corrosion / irritation

Reason for no classification:

data conclusive but not sufficient for classification

Serious eye damage / eye irritation

Hazard category:

Eye Damage 1

Hazard statement:

H318: Causes serious eye damage.

Respiratory sensitisation

Reason for no classification:

data lacking

Skin sensitisation

Reason for no classification:

data conclusive but not sufficient for classification

Aspiration hazard

Reason for no classification:

data lacking

Reproductive toxicity

Hazard category:

Repr. 1B

Hazard statement:

H360: May damage fertility or the unborn child <state specific effect if known > <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Specific effect:

F,D; Characteristic syndrome of oropharyngeal malformations following parental exposure via oral route.

Effects on or via lactation

Reason for no classification:

data lacking

Germ cell mutagenicity

Hazard category:

Muta. 2

Hazard statement:

H341: Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Carcinogenicity

Reason for no classification:

data lacking

1. Specific target organ toxicity - single (STOT-SE)

Hazard category:

STOT Single Exp. 1

Hazard statement:

H370: Causes damage to organs <or state all organs affected, if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Affected organs:

thymus

Route of exposure:

oral

1. Specific target organ toxicity - repeated (STOT-RE)

Hazard category:

STOT Rep. Exp. 1

Hazard statement:

H372: Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Affected organs:

thymus

Specific concetration limits

1.

Concentration range (%):

>= 0.6

Hazard categories:

Repr. 1B

2.

Concentration range (%):

>= 2

Hazard categories:

Muta. 2

3.

Concentration range (%):

>= 2 - < 20

Hazard categories:

STOT Rep. Exp. 2

STOT Single Exp. 2

4.

Concentration range (%):

>= 20

Hazard categories:

STOT Rep. Exp. 1

STOT Single Exp. 1

Environmental hazards

Hazardous to the aquatic environment (acute / short-term)

Reason for no classification:

data conclusive but not sufficient for classification

Hazardous to the aquatic environment (long-term)

Hazard category:

Aquatic Chronic 4

Hazard statement:

H413: May cause long lasting harmful effects to aquatic life.

Hazardous to the ozone layer

Reason for no classification:

data lacking

Labelling

Signal word:

Danger

Hazard pictogram

GHS02: flame

GHS05: corrosion

GHS07: exclamation mark

GHS08: health hazard

Hazard statements

H332: Harmful if inhaled.

H226: Flammable liquid and vapour.

H302: Harmful if swallowed.

H318: Causes serious eye damage.

H341: Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H360: May damage fertility or the unborn child <state specific effect if known > <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

F,D; Characteristic syndrome of oropharyngeal malformations following parental exposure via oral route.

H370: Causes damage to organs <or state all organs affected, if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Thymus

H372: Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Thymus

H413: May cause long lasting harmful effects to aquatic life.

Precautionary statements

P201: Obtain special instructions before use.

P202: Do not handle until all safety precautions have been read and understood.

P260: Do not breathe dust/fume/gas/mist/vapours/spray.

P264: Wash ... thoroughly after handling.

P270: Do not eat, drink or smoke when using this product.

P272: Contaminated work clothing should not be allowed out of the workplace.

P273: Avoid release to the environment.

P280: Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P281: Use personal protective equipment as required.

P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310: Immediately call a POISON CENTER/doctor/…

P321: Specific treatment (see ... on this label).

P333+P313: If skin irritation or rash occurs: Get medical advice/attention.

P363: Wash contaminated clothing before reuse.

P391: Collect spillage.

P405: Store locked up.

P501: Dispose of contents/container to ...