Copper hydroxide nitrate (Cu2(OH)3(NO3))

Auto flammability

Administrative data

Endpoint:

relative self-ignition temperature (solids)

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2001

Reliability:

1 (reliable without restriction)

Cross-reference

Cross-reference 1

Reason / purpose for cross-reference:

reference to same study

Reference

Endpoint:

appearance / physical state / colour

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2001

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Qualifier:

according to guideline

Guideline:

other: OECD 102

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Remarks:

Bundesministerium für Land- und Forstwirtschaft Umwelt und Wasserwirtschaft, Vienna, Austria

Physical state at 20°C and 1013 hPa:

solid

Form:

powder

Colour:

light blue

Odour:

odourless

Substance type:

inorganic

Conclusions:

The substance is a light blue, odourless powder.

Cross-reference 2

Reason / purpose for cross-reference:

reference to same study

Reference

Endpoint:

explosiveness

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2001

Reliability:

1 (reliable without restriction)

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

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reference to same study

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reference to same study

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reference to same study

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reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Qualifier:

according to guideline

Guideline:

other: BAM Hammer fall test

Deviations:

no

Qualifier:

according to guideline

Guideline:

other: BAM friction test

Deviations:

no

Qualifier:

according to guideline

Guideline:

other: Koenen steel tube test

Deviations:

no

Qualifier:

according to guideline

Guideline:

EU Method A.14 (Explosive properties)

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Remarks:

Bundesministerium für Land- und Forstwirtschaft Umwelt und Wasserwirtschaft, Vienna, Austria

Parameter:

other: More sensitive to shock than m-dinitrobenzene

Remarks:

migrated information

Remarks on result:

negative (not further specified)

Parameter:

other: More sensitive to friction than m-dinitrobenzene

Remarks:

migrated information

Remarks on result:

negative (not further specified)

Parameter:

other: Explosive under influence of flame

Remarks:

migrated information

Remarks on result:

negative (not further specified)

Parameter:

other: Explosive (not specified)

Remarks:

migrated information

Remarks on result:

negative (not further specified)

Conclusions:

copper hydroxide nitrate has no explosive properties with regard to shock, frition or thermal stress

Cross-reference 3

Reason / purpose for cross-reference:

reference to same study

Reference

Endpoint:

flammable solids

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2001

Reliability:

1 (reliable without restriction)

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

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reference to same study

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reference to same study

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reference to same study

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reference to same study

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reference to same study

Reason / purpose for cross-reference:

reference to same study

Qualifier:

according to guideline

Guideline:

EU Method A.10 (Flammability (Solids))

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Remarks:

Bundesministerium für Land- und Forstwirtschaft Umwelt und Wasserwirtschaft, Vienna, Austria

Test procedure:

burning time (test type not further specified)

Remarks:

or specified in description of method (migrated information)

Burning time:

240 s

Test procedure:

ignition time on contact with air

Remarks:

Ignition on contact with air refers to either Pyrophoric solids or Pyrophoric liquids depending on physical state (migrated information).

Remarks on result:

no ignition on contact with air (not further specified)

Remarks:

corresponding to 'no' in migrated source record.

Test procedure:

ignition time on contact with air

Remarks:

Ignition on contact with air refers to either Pyrophoric solids or Pyrophoric liquids depending on physical state (migrated information).

Remarks on result:

no ignition on contact with air (not further specified)

Remarks:

corresponding to 'no' in migrated source record.

Interpretation of results:

flammable

Remarks:

Migrated information

Conclusions:

the substance is not classified as highly flammable

Cross-reference 4

Reason / purpose for cross-reference:

reference to same study

Reference

Endpoint:

melting point/freezing point

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2001

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

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reference to same study

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reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Qualifier:

according to guideline

Guideline:

OECD Guideline 102 (Melting point / Melting Range)

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Remarks:

Bundesministerium für Land- und Forstwirtschaft Umwelt und Wasserwirtschaft, Vienna, Austria

Type of method:

capillary method

Melting / freezing pt.:

> 390 °C

Atm. press.:

1 013 hPa

Decomposition:

yes

Decomp. temp.:

> 235 °C

Conclusions:

The test substance decomposes from about 235°C and and has no melting point up to 390°C.

Cross-reference 5

Reason / purpose for cross-reference:

reference to same study

Reference

Endpoint:

oxidising solids

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2001

Reliability:

1 (reliable without restriction)

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

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reference to same study

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reference to same study

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reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Qualifier:

according to guideline

Guideline:

EU Method A.17 (Oxidising Properties (Solids))

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Remarks:

Bundesministerium für Land- und Forstwirtschaft Umwelt und Wasserwirtschaft, Vienna, Austria

Sample tested:

test mixture (not specified)

Remarks:

migrated information

Parameter:

maximum burning rate

Result:

0.704 other: mm/s (migrated information)

Remarks on result:

other: 60 % test substance

Sample tested:

test mixture (not specified)

Remarks:

migrated information

Parameter:

maximum burning rate

Result:

2.105 other: mm/s (migrated information)

Remarks on result:

other: 80% test substance

Interpretation of results:

other: oxidising: maximum burning rate equal or higher than reference mixture

Remarks:

Migrated information

Conclusions:

copper hydroxide nitrate is to classiefied as oxidising

Cross-reference 6

Reason / purpose for cross-reference:

reference to same study

Reference

Endpoint:

partition coefficient

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2001

Reliability:

1 (reliable without restriction)

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

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reference to same study

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reference to same study

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reference to same study

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reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Qualifier:

according to guideline

Guideline:

OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake Flask Method)

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Remarks:

Bundesministerium für Land- und Forstwirtschaft Umwelt und Wasserwirtschaft, Vienna, Austria

Type of method:

shake-flask method to: flask method

Partition coefficient type:

octanol-water

Type:

log Pow

Partition coefficient:

ca. 3.5

Temp.:

20 °C

pH:

> 5 - < 5.2

Conclusions:

The maximum solubility of copper in n-octanol is 0.05 mg / L
The estimated log P_{OW} is approx. 3.5

Cross-reference 7

Reason / purpose for cross-reference:

reference to same study

Reference

Endpoint:

surface tension

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2001

Reliability:

1 (reliable without restriction)

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Qualifier:

according to guideline

Guideline:

OECD Guideline 115 (Surface Tension of Aqueous Solutions)

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Remarks:

Bundesministerium für Land- und Forstwirtschaft Umwelt und Wasserwirtschaft, Vienna, Austria

Type of method:

OECD harmonised ring method

Surface tension:

ca. 72 mN/m

Temp.:

20 °C

Conc.:

1 g/L

Conclusions:

The mean surface tension of a 1g/L solution of copper hydroxide nitrate was determined to be 72.23 mN/m

Cross-reference 8

Reason / purpose for cross-reference:

reference to same study

Reference

Endpoint:

vapour pressure

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2001

Reliability:

1 (reliable without restriction)

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Qualifier:

according to guideline

Guideline:

OECD Guideline 104 (Vapour Pressure Curve)

Deviations:

no

Qualifier:

according to guideline

Guideline:

EU Method A.4 (Vapour Pressure)

Deviations:

no

GLP compliance:

yes

Remarks:

The Department of Health of the goverment of the United Kinddom, London, UK

Type of method:

effusion method: vapour pressure balance

Temp.:

25 °C

Vapour pressure:

< 0.001 Pa

Transition / decomposition:

no

Conclusions:

The test material has been determined to have a vapour pressure of less then 5.2x10^{-4} Pa at 25°C

Cross-reference 9

Reason / purpose for cross-reference:

reference to same study

Reference

Endpoint:

water solubility

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2001

Reliability:

1 (reliable without restriction)

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Qualifier:

according to guideline

Guideline:

OECD Guideline 105 (Water Solubility)

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Remarks:

Bundesministerium für Land- und Forstwirtschaft Umwelt und Wasserwirtschaft, Vienna, Austria

Type of method:

flask method

Water solubility:

153 other: mg Cu / L

Temp.:

20 °C

pH:

> 5 - < 5.2

Water solubility:

313.7 other: mg Cu / L

Temp.:

30 °C

pH:

> 5 - < 5.1

Water solubility:

41.9 other: mg Cu / L

Temp.:

10 °C

pH:

> 5.4 - < 6.3

Conclusions:

Interpretation of results (migrated information): moderately soluble (100-1000 mg/L)
The mean concentration of copper as part of copper hydroxide nitrate was 153.0 mg Cu / L according 578.97 mg / L copper hydroxide nitrate.

Data source

Reference

Reference Type:

study report

Title:

Unnamed

Year:

2001

Report date:

2001

Materials and methods

Test guideline

Qualifier:

according to guideline

Guideline:

EU Method A.16 (Relative Self-Ignition Temperature for Solids)

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Remarks:

Bundesministerium für Land- und Forstwirtschaft Umwelt und Wasserwirtschaft, Vienna, Austria

Test material

Test material information

Constituent 1

Reference substance name:

-

EC Number:

439-590-3

EC Name:

-

Cas Number:

12158-75-7

Molecular formula:

Hill: Cu2(OH)3NO3 CAS:

IUPAC Name:

copper(2+) hydroxide nitrate

Details on test material:

CAS# 12158-75-7, Batch 060248

Results and discussion

Relative self-ignition temperature (solids)

Relative self-ignition temperature:

> 700 °C

Remarks on result:

other: No self ignition temperature was found

Remarks:

at atm. press. of 1013.0 hPa

Applicant's summary and conclusion

Conclusions:

No self ignition temperature was determined in both tests