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Physical & Chemical properties

Flash point

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Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
18 November 2014
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
ISO 2719 (Determination of flash point - Pensky-Martens closed cup method)
Version / remarks:
2002
GLP compliance:
no
Type of method:
closed cup
Flash point apparatus:
Pensky-Martens apparatus
Key result
Flash point:
150 °C
Atm. press.:
997.4 hPa

Table 1. Flash point results from preliminary test

Amount of test item (g) Temperature (°C) Ignition (+/-) Air pressure (hPa)
63.07 148.0 + 997.4

Table 2. Flash point results from main test

Amount of test item (g) Temperature (°C) Ignition (+/-) Air pressure (hPa) Corrected flash point (°C)
62.56 149 + 997.4 149.39
60.98 151 + 997.4 151.39

In the preliminary test the lowest temperature where an ignition was observed was 148.0 °C. In the main test the lowest temperature where an ignition was observed was 149.0 °C. The average measured flash point is corrected to the ambient pressure to be 150.39 °C. The resulting average corrected flash point rounded down to the nearest multiple of 0.5 °C is 150.0 °C.

According to the results of the test on the flash point, the test item is classified as follows:

UN Transport Regulation: With a measured flash point > 60 °C, the test item does not have to be classified as flammable liquid in class 3 according to the UN Transport Regulation.

GHS (CLP Regulation EC 1272/2008 Annex 1: 2.6): With a measured flash point > 60 °C, the test item does not have to be classified as flammable liquid according to GHS or CLP Regulation EC 1272/2008 Annex 1.

Directive 67/548/EEC: With a measured flash point ≥ 55 °C the test item does not have to be classified as flammable liquid or mixture.

Interpretation of results:
GHS criteria not met
Conclusions:
The test item has a flash point of 150.0°C.
Executive summary:

The study was carried out according to EU method A.9 and is reliable without restriction (Klimisch 1). The test item has a flash point of 150.0°C at 997.4 hPa, as determined by closed cup method. With a measured flash point > 60 °C, the test item is not classified as a flammable liquid according to GHS or CLP Regulation EC 1272/2008 Annex 1.

Description of key information

The test item has a flash point of 150.0°C at 997.4 hPa, as determined by closed cup method.

Key value for chemical safety assessment

Flash point at 101 325 Pa:
150 °C

Additional information

The study was carried out according to EU method A.9 and is reliable without restriction (Klimisch 1) (2015). The test item has a flash point of 150.0°C at 997.4 hPa, as determined by closed cup method. With a measured flash point > 60 °C, the test item is not classified as a flammable liquid according to GHS or CLP Regulation EC 1272/2008 Annex 1.