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Diss Factsheets

Physical & Chemical properties

Auto flammability

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2015-11-02 to 2015-11-05
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Auto-ignition temperature:
299 °C
Atm. press.:
1 013 hPa
Remarks on result:
other: The auto-ignition temperature of the test item was 299±3°C (corrected temperature).

Results:

Preliminary study

The results for the preliminary study are shown in the table below

Volume of test item injected in the oven: 70 µL

 

 

Temperature of the assay(°C)

Auto-ignition

Maximal temperature of the air recorded in the center of the test flask after auto-ignition(°C)

Atmospheric pressure(kPa)

Relative humidity(%)

Run No.

Observed

Corrected

Y / N

Lag(s)

Observed

Corrected

1

101

101

No

/

/

/

98.8

44

2

150

150

No

/

/

/

98.7

43

3

200

200

No

/

/

/

98.8

43

4

250

250

No

/

/

/

98.8

43

5

310

310

Yes

6

334

333

98.5

43

6

284

284

No

/

/

/

98.5

44

7

296

296

No

/

/

/

98.4

45

8

300

300

Yes

15

321

321

98.4

46

 

The auto-ignition temperature was situated between 296°C and 300°C (corrected values). This range is given for information, the final result is given by the main test in following section.

Main study:

The results for the main study are shown in the table below

Volume of test item injected in the oven: 70 µL

Only the runs with an auto-ignition observed for each assay are summarised in the following table:

 

Auto-ignition temperature(°C)

Auto-ignition

Maximal temperature of the air recorded in the center of the test flask after ignition(°C)

Atmospheric pressure
(kPa)

Relative humidity
(%)

Assay No.

Observed

Corrected

Lag(s)

Observed

Corrected

1

299

299

19

322

322

98.4

48

2

301

301

19

324

324

98.7

48

3

301

301

16

322

322

98.6

49

4

301

301

17

323

323

98.5

52

5

302

302

14

323

323

98.6

49

 

Conclusions:
An auto-ignition temperature value of 299±3°C at 1013 hPa was obtained for the substance using a relevant test method and in compliance with GLP. The result is considered to be reliable.

Description of key information

Auto-ignition temperature: 299±3°C at 1013 hPa (EU Method A.15)

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
299 °C

Additional information

A measured auto-ignition temperature value of 299±3°C at 1013 hPa was determined for the registration substance using a relevant test method and in compliance with GLP. The result is considered to be reliable.