Registration Dossier
Registration Dossier
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EC number: 700-093-4 | CAS number: 176969-34-9
Flammability
Administrative data
- Endpoint:
- self-heating substances / mixtures
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 2020
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 020
- Report date:
- 2020
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- UN Manual of Tests and Criteria: Test N.4 (Test method for self-heating substances)
- GLP compliance:
- yes (incl. QA statement)
- Remarks:
- Hessisches Ministerium für Umwelt, Klimaschutz, Landwirtschaft und Verbraucherschutz
Test material
- Reference substance name:
- 3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxylic acid
- EC Number:
- 700-093-4
- Cas Number:
- 176969-34-9
- Molecular formula:
- C6H6F2N2O2
- IUPAC Name:
- 3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxylic acid
Constituent 1
Results and discussion
Self-heating substances / mixtures
- Key result
- Test procedure:
- 100 mm sample cube at 140°C
- Max. temp. reached:
- 140
- Induction time (h):
- 9
- Result:
- negative outcome (no effect observed)
Any other information on results incl. tables
For the test in the 10 cm cube at an oven temperature of 140 °C ±2 °C an amount of 733.3 g of the test item was filled in the sample container. The test item temperature reached the oven temperature (141 °C) after approximately 9 hours. After at least 24 hours the test was stopped without detecting exothermal effects. The maximum sample temperature was 139 °C.
After the measurement the mesh wire basket contained approximately 2 wt.% less test item than at the start. The remaining test item showed no visual changes.
Due to the negative result at 140 °C (10 cm cube) the test item had not to be classified as "self-heating substance" in the sense of UN Manual of Tests and Criteria, Method N.4., and had not to be classified as "self-heating substance" according to chapter 2.1 Il of the GHS (CLP) regulations.
Applicant's summary and conclusion
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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