Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Endpoint summary

Administrative data

Description of key information

Additional information

Stability

Phototransformation in air

Parent compound propyl chloroformate (CAS 109-61-5):

After evaporation or exposure to air, the substance will be slowly degraded by photochemical processes. This estimation refers to dry air. In mist, rain, droplets and aerosols hydrolysis will be the major fate process of the substance due to the short half-life in aqueous solutions. Therefore this estimate may be of low relevance.

Hydrolysis product propanol (CAS 71-23-8):

After evaporation or exposure to air, the substance will be slowly degraded by photochemical processes.

Hydrolysis

Parent compound propyl chloroformate (CAS 109-61-5):

In contact with water, the substance will hydrolyse rapidly.

Hydrolysis product propanol (CAS 71-23-8).

According to structural properties, hydrolysis is not expected.

 

Biodegradation

Parent compound propyl chloroformate (CAS 109-61-5):

Hydrolyses rapidly (half-life = 29.5 min)

 

Hydrolysis product propanol (CAS 71-23-8):

Readily biodegradable according to OECD criteria.

 

Bioaccumulation

Parent compound propyl chloroformate (CAS 109-61-5):

Significant accumulation in organisms is not to be expected.

 

Hydrolysis product propanol (CAS 71-23-8):

Significant accumulation in organisms is not to be expected.

 

 

Transport and distribution

Adsorption / desorption

Parent compound propyl chloroformate (CAS 109-61-5)

Adsorption to the solid soil phase is not expected. However, propyl chloroformate (CAS 1409-61-5) rapidly decomposes in water. Therefore, the model calculation may be of low relevance.

Hydrolysis product propanol (CAS 71-23-8).

Adsorption to the solid soil phase is not expected.

Henry's Law Constant

Parent compound propyl chloroformate (CAS 109-61-5):

From the water surface, the substance will rapidly evaporate into the atmosphere. However, propyl chloroformate is rapidly hydrolysed to propanol, CO2 and HCl.

Hydrolysis product propanol (CAS 71-23-8).

From the water surface, the substance will not evaporate into the atmosphere.