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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flash point

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Administrative data

Endpoint:
flash point
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
2008-12-08 to 2008-12-15
Reliability:
1 (reliable without restriction)
Cross-referenceopen allclose all
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to other study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2008
Report date:
2008

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
ISO No., other: DIN EN ISO 17736
Deviations:
no
Principles of method if other than guideline:
NA
GLP compliance:
not specified
Type of method:
closed cup

Test material

Constituent 1
Chemical structure
Reference substance name:
Butyllithium
EC Number:
203-698-7
EC Name:
Butyllithium
Cas Number:
109-72-8
Molecular formula:
C4H9Li
IUPAC Name:
butyllithium
Details on test material:
- Name of test material (as cited in study report): n-Butyllithium 90% in hexane
- Lot/batch No.: 145-0

Results and discussion

Flash point
Flash point:
< -13.9 °C

Any other information on results incl. tables

No remarks

Applicant's summary and conclusion

Conclusions:
The determination of the flash point was performed with n-Butyllithium 90% in hexane according to DIN EN ISO 17736. Based on this a preliminary flashpoint of lower than - 13.9 degree C was found. No reliable results were obtained with a standard OECD test. But the handling caused a risk to the laboratory staff.
Executive summary:

The determination of the flash point was performed with n-Butyllithium 90% in hexane according to DIN EN ISO 17736. Based on this a preliminary flashpoint of lower than - 13.9 degree C was found. However, after the substance was poured out of the cup, self ignition occurred and the flame was extinguished by means of nitrogen. The remaining sample amount was diluted with n-heptane to a concentration of about 5 to 10 %. No further experiments were performed due to risk in handling the substance. Again, no reliable results were obtained with a standard OECD test. But the handling caused a risk to the laboratory staff.