Registration Dossier
Registration Dossier
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EC number: 224-698-3 | CAS number: 4454-05-1
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Description of first aid measures
Remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide
5.2. Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.
5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
6.2. Environmental precautions
Do not discharge into drains/surface waters/groundwater.
6.3. Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations.
6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.
Handling and storage
7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:
Take precautionary measures against static discharges.
7.2. Conditions for safe storage, including any incompatibilities
Suitable materials for containers: Carbon steel (Iron), Stainless steel 1.4301 (V2), Stainless steel 1.4401, High density polyethylene (HDPE), Low density polyethylene (LDPE), Polyester resin, glass reinforced (Palatal A410)
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Storage stability:
Storage duration: 12 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
7.3. Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
8.1. Control parameters
Components with occupational exposure limits
67-56-1: methanol
Skin Designation (OEL (EU))
The substance can be absorbed through the skin.
TWA value 260 mg/m3 ; 200 ppm (OEL (EU))
indicative
Short Term Exposure Classification: (TRGS 900 (DE))
Category II: Substances with a resorptive effect
OEL 270 mg/m3 ; 200 ppm (TRGS 900 (DE))
Ceiling limit value/factor: 4
If the occupational exposure limit value (AGW) and the biological limit value (BGW) are complied with, there should be no risk of damage for the unborn child (see TRGS 900, Number 2.7)
Skin Designation (TRGS 900 (DE))
The substance can be absorbed through the skin.
PNEC
freshwater: 0,1 mg/l
marine water: 0,01 mg/l
intermittent release: 1 mg/l
STP: 3806,04 mg/l
sediment (freshwater): 0,212 mg/kg
sediment (marine water): 0,0212 mg/kg
soil: 0,0163 mg/kg
oral (secondary poisoning):
No PNEC value available.
DNEL
No DNEL value available.
8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
fluoroelastomer (FKM) - 0.7 mm coating thickness
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374)
nitrile rubber (NBR) - 0.4 mm coating thickness
butyl rubber (butyl) - 0.7 mm coating thickness
polyvinylchloride (PVC) - 0.7 mm coating thickness
chloroprene rubber (CR) - 0.5 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. The substance was registered as a transported isolated intermediate. The manufacturer/importer has received the confirmation by the user that the substance is used under strictly controlled conditions in accordance with art. 18 of the REACH regulation (EC) No 1907/2006.
Stability and reactivity
10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated. The product may become unstable at elevated temperatures and under pressure.
10.3. Possibility of hazardous reactions
Reacts with amines. The progress of reaction is exothermic.
10.4. Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame. See MSDS section 7 - Handling and storage.
10.5. Incompatible materials
Substances to avoid:
amines
10.6. Hazardous decomposition products
Hazardous decomposition products:
carbon oxides
Disposal considerations
13.1. Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
