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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

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Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
11.11.2014 to 20.11.2014
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: GLP-Study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2015
Report date:
2015

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: Guideline VDl 2263, sheet 1 (Grewer-oven)
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: UN Recommendations on the Transport of Dangerous Goods, fifth revised edition, 2009, Appendix 6
Deviations:
no
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
Sodium 2-methylbutan-2-olate
EC Number:
238-639-4
EC Name:
Sodium 2-methylbutan-2-olate
Cas Number:
14593-46-5
Molecular formula:
C5H12O.Na
IUPAC Name:
sodium 2-methylbutan-2-olate
Test material form:
solid: particulate/powder
Remarks:
migrated information: powder

Results and discussion

Relative self-ignition temperature (solids)
Relative self-ignition temperature:
110 °C
Remarks on result:
other:

Any other information on results incl. tables

The temperature of the test item showed an exothermal effect starting at 110°C.

Applicant's summary and conclusion

Conclusions:
According to the guideline VDl 2263, sheet 1 (Grewer-Oven) a self-ignition was observed at 110 °C. Due to these results further tests are
necessary for the classification of the test item according to the UN Recommendations on the Transport of Dangerous Goods
(Manual of Tests and Criteria rev. 5) and to the GHS Regulations and Regulation (EC) 1272/2008 (CLP).
Result: self-iginition positive.
Executive summary:

According to the guideline VDl 2263, sheet 1 (Grewer-Oven) a self-ignition was observed at 110 °C. Due to these results further tests are necessary for the classification of the test item according to the UN Recommendations on the Transport of Dangerous Goods (Manual of Tests and Criteria rev. 5) and to the GHS Regulations and Regulation (EC) 1272/2008 (CLP).