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Diss Factsheets

Physical & Chemical properties

Flammability

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Administrative data

Link to relevant study record(s)

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Endpoint:
pyrophoric solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2010-06-07
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
UN Manual of Tests and Criteria: Test N.2 (Test method for pyrophoric solids)
GLP compliance:
yes
Test procedure:
ignition time on contact with air
Remarks on result:
no ignition on contact with air (not further specified)

It has been determined that the test substance was not classified as a pyrophoric solid of class 4.2.

Runs

Ignition/No ignition

Observations

1

No ignition

No reaction

2

No ignition

No reaction

3

No ignition

No reaction

4

No ignition

No reaction

5

No ignition

No reaction

6

No ignition

No reaction

Interpretation of results:
other: not classified based on EU GHS criteria
Conclusions:
It has been determined that the test substance was not classified as a pyrophoric solid according to UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria for substances of Class 4, Division 4.2.
Executive summary:

The pyrophoric properties of the test item was assessed in a GLP-conform study according to UN Manual of Tests and Criteria: Test N.2. No observations was made that leads to a classification.

Endpoint:
flammable solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2010-06-02
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
EU Method A.10 (Flammability (Solids))
Deviations:
not specified
Qualifier:
according to guideline
Guideline:
UN Manual of Tests and Criteria: Test N.1 (Test method for readily combustible solids)
Deviations:
not specified
Qualifier:
according to guideline
Guideline:
other: HSE Code of Physico-Chemical Properties 1982
Deviations:
not specified
GLP compliance:
yes
Test procedure:
burning rate test over 100 mm length
Remarks on result:
substance does not ignite and propagate combustion either by burning with flame or smouldering along 200 mm of the powder train within the 2 minutes test period

In the preliminary test the sample did not ignite and therefore no further testing was required. Initially the sample melted to a clear paste, boiled and glowed red while in contact with the ignition source. No propagation of the reaction was observed.

Interpretation of results:
other: EU GHS criteria not met
Conclusions:
It was determined that the test substance should be classified as "not a highly flammable solid".
Executive summary:

The test item was assessed for its flammability-properties in a GLP-conform study according to EU method A.10, UN Manual of Tests and Criteria: Test N.1 (Test method for readily combustible solids) and HSE Code of Physico-Chemical properties 1982. The sample did not ignite. Initially the sample melted to a clear paste, boiled and glowed red while in contact with the ignition source. No propagation of the reaction was observed.

Description of key information

Flammability:

The test item was assessed for its flammability-properties in a GLP-conform study according to EU method A.10, UN Manual of Tests and Criteria: Test N.1 (Test method for readily combustible solids) and HSE Code of Physico-Chemical properties 1982. The sample did not ignite. Initially the sample melted to a clear paste, boiled and glowed red while in contact with the ignition source. No propagation of the reaction was observed.

Pyrophoricity:

The pyrophoric properties of the test item was assessed in a GLP-conform study according to UN Manual of Tests and Criteria: Test N.2. No observations was made that leads to a classification.

Key value for chemical safety assessment

Flammability:
non flammable

Additional information

Justification for classification or non-classification