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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
oxidising liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
20 May 2022
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2022
Report date:
2022

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
UN Manual of Tests and Criteria: Test O.2 (Test for oxidizing liquids)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Remarks:
GLP certifying authority: Ministerium für Arbeit, Gesundheit und Soziales des Landes Nordrhein-Westfalen, Düsseldorf, Germany

Test material

Constituent 1
Chemical structure
Reference substance name:
2-nitro-4-(trifluoromethyl)benzonitrile
EC Number:
212-298-1
EC Name:
2-nitro-4-(trifluoromethyl)benzonitrile
Cas Number:
778-94-9
Molecular formula:
C8H3F3N2O2
IUPAC Name:
2-nitro-4-(trifluoromethyl)benzonitrile

Study design

Contact with:
powdered cellulose

Results and discussion

Test results (Oxidising liquids)open allclose all
Sample tested:
reference mixture with 65% nitric acid + cellulose (1:1 ratio)
Parameter:
mean pressure rise time
Result:
1.65 s
Remarks on result:
other: The mean value of the last five reference tests is 2.02 s. The deviation of the new reference value is -18 %.
Sample tested:
test mixture 1:1
Parameter:
mean pressure rise time
Result:
5.4 s
Remarks on result:
other: The time for pressure rise is between 4.6-6.5 s, the maximum deviation of the mean value is 18 %. As the times for pressure rise obtained for the test item exceed the reference value, all runs may be used for reporting.

Any other information on results incl. tables
































Mixture (1:1)Time for Pressure Rise
from 690 kPa to 2070 kPa
Nitric acid (65%) / Cellulose (reference)1.65 s
Test item / Cellulose No. 16.5 s
Test item / Cellulose No. 25.0 s
Test item / Cellulose No. 35.4 s
Test item / Cellulose No. 44.6 s
Test item / Cellulose No. 55.5 s

The mean value of the last five reference tests is 2.02 s. The deviation of the new reference value is -18 %.
The mean value of all tests is 5.4 s, the maximum deviation of the mean value is 18 %. As the times for pressure rise obtained for the test item exceed the reference value, all runs may be used for reporting.


All determined values for the pressure rise from 690 to 2070 kPa of the given sample exceed the obtained value for the reference measurement. Therefore, the test item is to be classified to have no oxidizing properties according to UN-MTC.

Applicant's summary and conclusion

Interpretation of results:
GHS criteria not met
Conclusions:
All determined values for the pressure rise from 690 to 2070 kPa of the given sample exceed the obtained value for the reference measurement. The sample is to be classified to have no oxidizing properties according to UN-MTC.