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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Explosiveness

Currently viewing:

Administrative data

Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2016
Report date:
2016

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: UN Recommendations on the Transport of Dangerous Goods, "Manual of Tests und Criteria", 5th revised version, Tests 1(b) and 2(b) (classification of substances of class 1) and E.1 (classification of substances of division 4.1)
Deviations:
no
GLP compliance:
no
Other quality assurance:
ISO/IEC 17025 (General requirements for the competence of testing and calibration laboratories)

Test material

Constituent 1
Chemical structure
Reference substance name:
Nitrotoluene
EC Number:
215-311-9
EC Name:
Nitrotoluene
Cas Number:
1321-12-6
Molecular formula:
C7H7NO2
IUPAC Name:
Toluene, reaction product with nitrosulphuric acid (mixture of concentrated nitric acid and concentrated sulphuric acid)
Details on test material:
- Name of test material (as cited in study report): Rück-MNT

Results and discussion

Small-scale preliminary testsopen allclose all
Parameter:
other: More sensitive to shock than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Parameter:
other: More sensitive to friction than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Parameter:
other: Explosive under influence of flame
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Parameter:
other: Explosive (not specified)
Remarks:
migrated information
Remarks on result:
negative (not further specified)

Any other information on results incl. tables

Results in detail:

Impact sensitivity:

Impact energy

Trial No.

Effect

 

1

No

 

2

No

40 J

3

No

 

4

No

 

5

No

 

6

No

Since none of the trials led to any explosion (bang and/or inflammation), the substance is not sensitive to impact.

Fricition sensitivity:

Trial No.

Explosion ?

Crepitation ?

Inflammation ?

1

No

No

No

2

No

No

No

3

No

No

No

4

No

No

No

5

No

No

No

6

No

No

No

The substance is not sensitive to friction.

Thermal sensivity

The limiting diameter, i.e. the largest diameter of the orifice at which "explosion" occurs, is: <1.0 mm

Assessment of the result within the meaning of test E.1 (related to Division 4.1): The effect of intensively heating the substance under high confinement is low.

Assessment of the result within the meaning of test 1(b) (related to Class 1): There is no effect from intensively heating the substance under high confinement .

Assessment of the result within the meaning of test 2(b) (related to Class 1): There is no violent effect from intensively heating the substance under high confinement .

Applicant's summary and conclusion