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Diss Factsheets

Physical & Chemical properties

Flammability

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Endpoint:
flammable solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
1992
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Study has been performed according to German guidelines by an independent laboratory.
Qualifier:
according to guideline
Guideline:
other: VDI 2263, Blatt 1: "Staubbrände und Staubexplosionen, Gefahren - Beurteilung - Schutzmaßnahmen; Untersuchungsmethoden zur Ermittlung von sicherheitstechnischen Kenngrößen von Stäuben"
GLP compliance:
not specified
Specific details on test material used for the study:
400-mesh powder (<30 µm) as commercially available
Key result
Test procedure:
other: screening test
Remarks:
VDI 2263
Remarks on result:
other: Flammability class
Remarks:
BZ2

Specific observation on the dusts were not provided. Commercial calcium boride powder was assigned a flammability class of BZ2. Filter dust (not commercially available) was assigned a flammability class of BZ4.

Interpretation of results:
non flammable
Conclusions:
According to the results of the evaluation on burning behaviour, BZ2 has been assigned to calcium hexaboride powder and BZ4 has been assigned to CaB6 filter dust. Based on the burning behaviour of CaB6 in this test, it can be concluded that CaB6 as commercialized does not have to be classified as highly flammable. No labelling is required for CaB6.
Executive summary:

The test was performed under a German national guideline (VDI 2263) by an authority involved in occupational safety. The method is considered a suitable screening level flammability test under CLP. The result is deemed reliable with restrictions and suitable for Classification & Labeling.

Endpoint:
flammable solids
Data waiving:
study scientifically not necessary / other information available
Justification for data waiving:
other:

Description of key information

Calcium hexaboride is not a flammable solid.

Key value for chemical safety assessment

Flammability:
not classified

Additional information

Flammable solids classification under CLP may be based on a result of BZ3 or lower in a test done under VDI 2263. The commercialized product was assigned BZ2 in a VDI 2263 test. No further testing is required of this inert substance.

Justification for classification or non-classification

Substance does not meet classification criteria in a screening level test.